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Structural Modulation and Enhanced Magnetic Ordering in Incommensurate KCrSe Crystals.
J Am Chem Soc
January 2025
Department of Quantum Matter Physics, University of Geneva, 24 Quai Ernest-Ansermet, CH-1211 Geneva, Switzerland.
Layered delafossite-type compounds and related transition metal dichalcogenides, characterized by their triangular net structures, serve as prototypical systems for exploring the intricate interplay between crystal structure and magnetic behavior. Herein, we report on the discovery of the compound KCrSe ( ≈ 0.13), an incommensurately modulated phase.
View Article and Find Full Text PDFQuasi-Two-Dimensional Antiferromagnetic Spin Fluctuations in the Spin-Triplet Superconductor Candidate CeRh_{2}As_{2}.
Phys Rev Lett
December 2024
Johns Hopkins University, Institute for Quantum Matter and Department of Physics and Astronomy, Baltimore, Maryland 21218, USA.
The tetragonal heavy-fermion superconductor CeRh_{2}As_{2} (T_{c}=0.3 K) exhibits an exceptionally high critical field of 14 T for B∥c. It undergoes a field-driven first-order phase transition between superconducting states, potentially transitioning from spin-singlet to spin-triplet superconductivity.
View Article and Find Full Text PDFTwo-Dimensional Magnetic Exciton Polariton with Strongly Coupled Atomic and Photonic Anisotropies.
Phys Rev Lett
December 2024
University of Michigan, Department of Physics, Ann Arbor, Michigan 48109, USA.
Anisotropy is a fundamental property of both material and photonic systems. The interplay between material and photonic anisotropies, however, has hardly been explored due to the vastly different length scales. Here we demonstrate exciton polaritons in a 2D antiferromagnet, CrSBr, coupled with an anisotropic photonic crystal cavity, where the spin, atomic, and photonic anisotropies are strongly correlated.
View Article and Find Full Text PDFAn Implicit Solvation Model for Binding Free Energy Estimation in Nonaqueous Solution.
J Phys Chem B
January 2025
Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, 76131 Karlsruhe, Germany.
Implicit solvation models permit the approximate description of solute-solvent interactions, where water is the most often considered solvent due to its relevance in biological systems. The use of other solvents is less common but is relevant for applications such as in nuclear magnetic resonance (NMR) or chromatography. As an example, chloroform is commonly used in anisotropic NMR to measure residual dipolar couplings (RDCs) of chiral analytes weakly aligned by an alignment medium.
View Article and Find Full Text PDFIn this paper the finite-difference time-domain general vector auxiliary differential equation method [Opt. Express14, 8305 (2006)10.1364/OE.
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