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Downscaling of Non-Van der Waals Semimetallic WN with Resistivity Preservation.
ACS Nano
January 2025
Department of Chemistry, Boston University, 590 Commonwealth Ave., Boston, Massachusetts 02215, United States.
The bulk phase of transition metal nitrides (TMNs) has long been a subject of extensive investigation due to their utility as coating materials, electrocatalysts, and diffusion barriers, attributed to their high conductivity and refractory properties. Downscaling TMNs into two-dimensional (2D) forms would provide valuable members to the existing 2D materials repertoire, with potential enhancements across various applications. Moreover, calculations have anticipated the emergence of uncommon physical phenomena in TMNs at the 2D limit.
View Article and Find Full Text PDF"Double-Use" Strategy for Improving the Photoelectrochemical Performance of BiVO Photoanodes Using a Cobalt-Functionalized Polyoxotungstate.
ACS Appl Mater Interfaces
January 2025
Institute of Electrochemistry, Ulm University, Albert-Einstein-Allee 47, Ulm 89081, Germany.
Doping and surface-modification are well-established strategies for the performance enhancement of bismuth vanadate (BiVO) photoanodes in photoelectrochemical (PEC) water splitting devices. Herein, a "double-use" strategy for the development of high-performance BiVO photoanodes for solar water splitting is reported, where a molecular cobalt-phosphotungstate (CoPOM = Na[Co(HO)(PWO)]) is used both as a bulk doping agent as well as a surface-deposited water oxidation cocatalyst. The use of CoPOM for bulk doping of BiVO is shown to enhance the electrical conductivity and improve the charge separation efficiency, resulting in the enhancement of the maximum applied-bias photoconversion efficiency (ABPE) by a factor of ∼18 to 0.
View Article and Find Full Text PDFHealing Trap States of Anomalous Antisite Defects via Surface Passivation in Lead Iodide Perovskites: A First-Principles Study.
Chemphyschem
January 2025
Department of Physics, Yingbin Road 688, Jinhua, CHINA.
Undesirable loss of open-circuit voltage and current of metal halide perovskite (MHP) solar cells are closely associated with defects, so theoretical calculations have been often performed to scrutinize the nature of defects in bulk of MHPs. Yet, exploring the properties of defects at surfaces of MHPs is severely lacking given the complexity of the surface defects with high concentrations. In this study, IPb (PbI) antisite defects, namely one Pb (I) site being occupied by one I (Pb) atom at the surfaces of the FAPbI3 (FA = CH(NH2)2) material, are found to create electron (hole) traps when the surfaces with IPb (PbI) antisite defects are negatively (positively) charged.
View Article and Find Full Text PDFHigh performance ozone nanobubbles based advanced oxidation processes (AOPs) for degradation of organic pollutants under high pollutant loading.
J Environ Manage
January 2025
Department of Sanitary Engineering, Faculty of Civil and Environmental Engineering, Gdansk University of Technology, Narutowicza 11/12 Str., 80-233, Gdansk, Poland; School of Civil, Environmental, and Architectural Engineering, College of Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul, 02841, Republic of Korea. Electronic address:
Advanced Oxidation Processes (AOPs) have proven to be an effective solution for chemical wastewater treatment, particularly for degradation of organic pollutants, especially dyes. Ozonation is recognized as one of the most prevalent AOPs. Nevertheless, some cases show a lowered efficiency of O utilization which is attributed to its inadequate distribution in the treated water causing low residence time, low mass transfer coefficient as well as shorter half-life.
View Article and Find Full Text PDFImproving the accuracy of temperature measurement on TEM samples using plasmon energy expansion thermometry (PEET): Addressing sample thickness effects.
Ultramicroscopy
January 2025
National Centre for Nano Fabrication and Characterization (DTU Nanolab), Technical University of Denmark (DTU), Kgs. Lyngby, Denmark. Electronic address:
Advances in analytical scanning transmission electron microscopy (STEM) and in microelectronic mechanical systems (MEMS) based microheaters have enabled in-situ materials' characterization at the nanometer scale at elevated temperature. In addition to resolving the structural information at elevated temperatures, detailed knowledge of the local temperature distribution inside the sample is essential to reveal thermally induced phenomena and processes. Here, we investigate the accuracy of plasmon energy expansion thermometry (PEET) as a method to map the local temperature in a tungsten (W) lamella in a range between room temperature and 700 °C.
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