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Transport equipment manufacturers in the automotive and aerospace industries are focused on developing materials that enhance fuel efficiency and reduce carbon dioxide emissions. A significant approach is employing lightweight materials like aluminum, magnesium, and polymer-based composites. Polyamide-based composites, particularly nylon 66, as viable alternatives due to their excellent rigidity, chemical resistance, and thermal stability are investigated to address the limitations of traditional thermosetting resins, which are difficult to recycle and have lengthy molding processes that hinder mass production.
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EaStCHEM, School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, UK.
Negative thermal expansion is known to exist in a range of structure types but is extremely rare in hexagonal perovskites. Here we demonstrate that BaIrO displays negative linear thermal expansion in the direction of its face-shared IrO trimers, and apparent zero volume thermal expansion below 100 K. We present evidence that this anomalous thermal expansion is driven by an unusual form of rigid body phonon behaviour governed by the effective trimer valence state and therefore has structural and electronic components to the underlying mechanism.
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Industrial Chemistry Laboratory, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis Zografou, 15771 Athens, Greece.
Well-defined amorphous/semi-crystalline statistical copolymers of n-dodecyl isocyanate, DDIC, and allyl isocyanate, ALIC, were synthesized via coordination polymerization using the chiral half-titanocene complex CpTiCl(O-(S)-2-Bu) as an initiator. In the frame of the terminal model, the monomer reactivity ratios of the statistical copolymers were calculated using both well-known linear graphical methods and the computer program COPOINT. The molecular and structural characteristics of the copolymers were also calculated.
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Faculty of Chemical Engineering and Technology, Cracow University of Technology, Warszawska 24, 31-155 Kraków, Poland.
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