Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1103/physrevb.53.9528 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Magnetoelectric and MIESST effects in spin crossover materials exhibiting symmetry-breaking.
Dalton Trans
June 2024
Univ Rennes, CNRS, IPR (Institut de Physique de Rennes) - UMR 6251, 35000 Rennes, France.
Giant magnetoelectric coupling and magnetic-field-induced spin state trapping (MIESST) were recently reported in spin crossover materials with polar phases. We discuss these phenomena considering the distinct contributions of the change of the molecular spin state, driven by the magnetic field, and the coupled structural symmetry-breaking during the stepwise change of electric polarisation or MIESST.
View Article and Find Full Text PDFCharge Puddles Driven Complex Crossover of Magnetoresistance in Non-Topological Sulfur Doped Antimony Selenide Nanowires.
Small
July 2024
UGC-DAE-Consortium for Scientific Research, University Campus, Khandwa Road, Indore, Madhya Pradesh, 452001, India.
A race to achieve a crossover from positive to negative magnetoresistance is intense in the field of nanostructured materials to reduce the size of memory devices. Here, the unusual complex magnetoresistance in nonmagnetic sulfur-doped SbSe nanowires is demonstrated. Intentionally, sulfur is doped in such a way to nearly achieve the charge neutrality point that is evident from switching of carrier type from p-type to n-type at 13 K as inferred from the low-temperature thermoelectric power measurements.
View Article and Find Full Text PDFMagnetoelectricity Enhanced by Electron Redistribution in a Spin Crossover [FeCo] Complex.
J Am Chem Soc
July 2023
Institute for Materials Chemistry and Engineering and IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka, 819-0395, Japan.
Molecular-based magnetoelectric materials are among the most promising materials for next-generation magnetoelectric memory devices. However, practical application of existing molecular systems has proven difficult largely because the polarization change is far lower than the practical threshold of the ME memory devices. Herein, we successfully obtained an [FeCo] dinuclear complex that exhibits a magnetic field-induced spin crossover process, resulting in a significant polarization change of 0.
View Article and Find Full Text PDFThermal and Magnetic Field Switching in a Two-Step Hysteretic Mn Spin Crossover Compound Coupled to Symmetry Breakings.
Angew Chem Int Ed Engl
January 2022
National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA.
A Mn spin crossover complex with atypical two-step hysteretic thermal switching at 74 K and 84 K shows rich structural-magnetic interplay and magnetic-field-induced spin state switching below 14 T with an onset below 5 T. The spin states, structures, and the nature of the phase transitions are elucidated via X-ray and magnetization measurements. An unusual intermediate phase containing four individual sites, where are in a pure low spin state, is observed.
View Article and Find Full Text PDFGiant Magnetoelectric Coupling and Magnetic-Field-Induced Permanent Switching in a Spin Crossover Mn(III) Complex.
Inorg Chem
May 2021
National High Magnetic Field Lab, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, United States.
We investigate giant magnetoelectric coupling at a Mn spin crossover in [MnL]BPh (L = (3,5-diBr-sal)323) with a field-induced permanent switching of the structural, electric, and magnetic properties. An applied magnetic field induces a first-order phase transition from a high spin/low spin (HS-LS) ordered phase to a HS-only phase at 87.5 K that remains after the field is removed.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!