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http://dx.doi.org/10.1103/physrevc.36.1649 | DOI Listing |
Dalton Trans
August 2016
School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, QLD 4072, Australia.
A series of lanthanide-based coordination polymers {[Yb1-xErx(4,4'-bpdo)3(H2O)2](CF3SO3)3}∞ were synthesised by solvent diffusion techniques, where 4,4'-bpdo = 4,4'-bipyridine-N,N'-dioxide, and using differing mole fractions of Yb(iii) and Er(iii) which were systematically varied (x = 0, 0.05, 0.20, 0.
View Article and Find Full Text PDFChemphyschem
December 2015
Department of Physics, Yogi Vemana University, Kadapa-, 516 003, India.
Er(3+) -Yb(3+) co-doped Lu3 Ga5 O12 nanogarnets were prepared and characterized; their structural and luminescence properties were determined as a function of the Yb(3+) concentration. The morphology of the nanogarnets was studied by HRTEM. Under 488 nm excitation, the nanogarnets emit green, red, and near-infrared light.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2015
College of Materials & Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, P. R. China.
Yb(3+)/Er(3+)/Cr(3+) triply doped transparent bulk glass ceramic containing orthorhombic YF3 and cubic Ga2O3 nanocrystals was fabricated by a melt-quenching route to explore its possible application in optical thermometry with high spatial and temperature resolution. It was experimentally observed that Yb(3+)/Er(3+) ions incorporated into the precipitated YF3 nanophase, while Cr(3+) ions partitioned into the crystallized Ga2O3 nanophase after glass crystallization. Importantly, such spatial isolation strategy efficiently suppressed adverse energy transfer among different active ions.
View Article and Find Full Text PDFPhys Chem Chem Phys
August 2015
Second Institute of Physics, University of Goettingen, Friedrich-Hund-Platz 1, 37077 Göttingen, Germany.
Ferroelectric BaTiO3 became a multifunctional material via doping of lanthanide ions (0.3 mol% Er(3+)/3.0 mol% Yb(3+)) and subsequently upconversion luminescence was enhanced by incorporation of Zn(2+) ions.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
November 2015
Department of Applied Physics, Indian School of Mines, Dhanbad 826005, Jharkhand, India.
Upconversion emission and temperature sensing of the Er(3+)/Yb(3+) doped ZnO-CaTiO3 nano-composite phosphor is studied by varying the ZnO concentration. The XRD and EDX studies reveal the formation of composite phase when ZnO doping exceeds above 10 mw%. Five prominent upconversion emission bands at 410, 492, 524, 545 and 662 nm corresponding to (2)H9/2→(4)I15/2, (4)F3/2→(4)I15/2, (2)H11/2→(4)I15/2, (4)S3/2→(4)I15/2 and (4)F9/2→(4)I15/2 transitions, respectively are found under 980 nm excitation from a diode laser.
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