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Light-driven hydrogen evolution catalyzed by a cobaloxime catalyst incorporated in a MIL-101(Cr) metal-organic framework.
Sustain Energy Fuels
June 2018
Uppsala University, Department of Chemistry - Ångström Laboratory, Box 523, 751 20 Uppsala, Sweden.
Article Synopsis
- A cobaloxime catalyst, Co(dmgH)(4-HEP)Cl, with a hydroxo-functionalized pyridine ligand, was studied for its ability to produce hydrogen (H) efficiently.
- The catalyst was immobilized on a chromium terephthalate metal-organic framework (MOF), MIL-101(Cr), creating a hybrid that showed improved photocatalytic activity for hydrogen evolution.
- While the lifespan of the cobaloxime catalyst improved with the MOF, its stability was restricted by the strength of the bond between cobalt and the pyridine ligand during catalytic reactions.
Viral infection modulation and neutralization by camelid nanobodies.
Proc Natl Acad Sci U S A
April 2013
Architecture et Fonction des Macromolécules Biologiques, Unité Mixte de Recherche 7257 Centre National de la Recherche Scientifique and Aix-Marseille University, 13288 Marseille Cedex 09, France.
Lactococcal phages belong to a large family of Siphoviridae and infect Lactococcus lactis, a gram-positive bacterium used in commercial dairy fermentations. These phages are believed to recognize and bind specifically to pellicle polysaccharides covering the entire bacterium. The phage TP901-1 baseplate, located at the tip of the tail, harbors 18 trimeric receptor binding proteins (RBPs) promoting adhesion to a specific lactococcal strain.
View Article and Find Full Text PDFMolecular mimicry: sensitization of Lewis rats with Campylobacter jejuni lipopolysaccharides induces formation of antibody toward GD3 ganglioside.
J Neurosci Res
February 2006
Institute of Molecular Medicine and Genetics and Institute of Neuroscience, Medical College of Georgia, Augusta, Georgia 30912-2697, USA.
Recently we have reported cases of demyelinating inflammatory neuropathy showing elevated titers of anti-GD3 antibodies, which occurs rarely in Guillain-Barré syndrome. To examine the correlation between the anti-GD3 antibody titer and Campylobacter jejuni infection, we sensitized female Lewis rats with lipopolysaccharides (LPSs) from serotype HS19 of C. jejuni and examined changes in nerve conduction velocity and nerve conduction block (P/D ratio).
View Article and Find Full Text PDFCalculations of depth-dose distributions, cross sections and momentum loss.
Adv Space Res
April 1998
GSI, Darmstadt, Germany.
The ability to know with precision the depth-dose, dose average LET, fluence and energy distributions is of great importance in many research fields, including therapeutic and diagnostic medicine when using heavy ion beams, as well as in space research. We have therefore developed a model and a computer code for calculating these distributions when using high energy proton or heavy ion beams. In this model, we use semi-empirical total reaction and partial cross section formulas developed by us and a new prescription to take into account the energy and momentum loss of the secondary nuclei.
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