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Superconductor-Insulator Transition Induced by Precise Subtripled Vapor Chemical Gating.
J Am Chem Soc
January 2025
State Key Laboratory of Precision and Intelligent Chemistry, CAS Key Laboratory of Mechanical Behavior and Design of Materials, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
Recent progress in superconductor-insulator transition has shed light on the intermediate metallic state with unique electronic inhomogeneity. The microscopic model, suggesting that carrier spatial distribution plays a decisive role in the intermediate state, has been instrumental in understanding the quantum transition. However, the narrow carrier density window in which the intermediate state exists necessitates precise control of the gate dielectric layer, presenting a challenge to in situ map the carrier spatial distribution.
View Article and Find Full Text PDFPlant diversity across dimensions: Coupling biodiversity measures from the ground and the sky.
Sci Adv
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Department of Ecology, Evolution and Behavior, University of Minnesota, 1479 Gortner Ave., Saint Paul, MN 55108, USA.
Tracking biodiversity across biomes over space and time has emerged as an imperative in unified global efforts to manage our living planet for a sustainable future for humanity. We harness the National Ecological Observatory Network to develop routines using airborne spectroscopic imagery to predict multiple dimensions of plant biodiversity at continental scale across biomes in the US. Our findings show strong and positive associations between diversity metrics based on spectral species and ground-based plant species richness and other dimensions of plant diversity, whereas metrics based on distance matrices did not.
View Article and Find Full Text PDFCarbon stock quantification and climate mitigation potential of a tropical moist forest in Ethiopia.
PLoS One
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Cooperative Agricultural Research Center, College of Agriculture, Food and Natural Resources, Prairie View A&M University, Prairie View, TX, United States of America.
The significance of forests in absorbing and storing carbon plays a crucial role in international greenhouse gas policies outlined by the United Nations Framework Convention for Climate Change (UNFCC). This study was conducted in a typical tropical moist forest of Ethiopia to assess its carbon stock, a critical issue in climate policy. The study domain was divided into six strata using elevation criteria.
View Article and Find Full Text PDFFunctional profiling of the sequence stockpile: a protein pair-based assessment of in silico prediction tools.
Bioinformatics
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Department of Biology, Emory University, Atlanta, GA 30322, United States.
Motivation: In silico functional annotation of proteins is crucial to narrowing the sequencing-accelerated gap in our understanding of protein activities. Numerous function annotation methods exist, and their ranks have been growing, particularly so with the recent deep learning-based developments. However, it is unclear if these tools are truly predictive.
View Article and Find Full Text PDFIncreasing the Orthogonality of 4-Pyridiniophenols: An NMR Study of Their Solvatomagnetism.
Magn Reson Chem
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Departamento de Química Orgánica y Fisicoquímica, Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Santiago, Chile.
The H- and C-NMR spectra of three substituted N-(4-hydroxyphenyl)pyridinium perchlorates, precursors of solvatochromic 4-pyridiniophenolate betaines, were recorded in deuterated acetone, dimethylsulfoxide, and acetonitrile, and their spectral behavior in these solvents was analyzed as evidence of the solute-solvent interactions present in solution. The effect of the increasing orthogonality between the phenolic and pyridinium fragments was clearly evident from the obtained spectra, thus shedding light on the ground-state structures of their deprotonated solvatochromic derivatives and their interactions with the solvent.
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