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FeS@BC prepared from natural pyrite and biomass as peroxydisulfate activator for sulfadiazine degradation.
Environ Res
January 2025
School of Environment and Energy Engineering, Anhui Jianzhu University, Hefei, 230601, China.
The efficient degradation of SAs is a significant challenge for the treatment of wastewater. To address this, the FeS@BC was prepared by calcining a mixture of pyrite and biomass, and used to activate peroxydisulfate (PDS) to degrade sulfadiazine (SDZ). The effect of carbon sources (wheat straw, rice husk, and corn cob) on catalytic activity of FeS@BC were investigated by Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), total Fe dissolution and free radical quantification.
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January 2025
Department of Medicinal Chemistry, School of Pharmaceutical Sciences, Wenzhou Medical University, Wenzhou, China.
Protein citrullination modification plays a pivotal role in the pathogenesis of rheumatoid arthritis (RA), and anti-citrullinated protein antibodies (ACPAs) are extensively employed for clinical diagnosis of RA. However, there remains limited understanding regarding specific citrullinated proteins and their implications in the progression of RA. In this study, we screen and verify insulin-like growth factor-2 mRNA binding protein 1 (IGF2BP1) as a novel citrullinated protein with significantly elevated citrullinated level in RA.
View Article and Find Full Text PDFBifunctional hierarchical WO nanorods@Br-doped g-CN Z-scheme heterojunctions for efficient tetracycline photodegradation: Optimization of key parameters, toxicological assessment, and electrocatalytic hydrogen evolution reaction.
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Department of Environmental Engineering, Kyungpook National University, 80 Daehak-ro, Buk-gu, Daegu, 41566, Republic of Korea. Electronic address:
In this study, graphitic carbon nitride (CN) and tungsten trioxide (WO) were successfully incorporated into bromine (Br)-doped graphitic carbon nitride (BCN) using an in-situ hydrothermal method. The photocatalytic efficiency of the resulting WO/Br-doped CN (WBCN) composites for the removal of tetracycline (TC) antibiotics under sunlight irradiation was evaluated. The mass ratio of WO to Br-doped CN (BCN) significantly influenced TC adsorption and photocatalytic degradation, with an optimal ratio of 9:1.
View Article and Find Full Text PDFWet scrubbing coupled with advanced oxidation process for removal of chlorobenzene: A study of performance and mechanisms.
Environ Res
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Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Kowloon, Hong Kong. Electronic address:
Porous graphitized carbon (PGC)-supported CoFeO bimetallic catalysts (CoFeO/PGC) were prepared by a hydrothermal method using Fe(NO)·9HO and Co(NO)·6HO as precursors and were used to activate peroxymonosulfate (PMS) for the degradation of chlorobenzene (CB). Under the conditions of CoFeO/PGC catalysts and PMS concentrations of 0.1 g/L and 5 mM, respectively, in a wide range of pH (5.
View Article and Find Full Text PDFPhotocatalytic Depolymerization of Lignin: C-O Bond Cleavage in β-O-4 Models Using S-Doped Ultra-Thin BiOCl Nanosheets.
Molecules
December 2024
School of Chemistry and Chemical Engineering, Guangxi Minzu University, Nanning 530006, China.
The selective depolymerization of β-O-4 lignin models into high-value aromatic monomers using photocatalysis presents both significant opportunities and challenges. Photocatalysts often face issues such as high photogenerated carrier recombination rates and limited operational lifetimes. This study introduces S doping to modulate the surface interface of BiOCl (BOC) nanosheets, enhancing C-O bond cleavage efficiency in β-O-4 lignin models under visible light at ambient temperatures.
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