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http://dx.doi.org/10.1103/physrevb.33.4373 | DOI Listing |
Molecules
December 2024
Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of RAS, 420088 Kazan, Russia.
In this study, comparative analysis of calculated and experimental C NMR shifts for a wide range of model platinum complexes showed that, on the whole, the theory reproduces the experimental data well. The chemical shifts of carbon atoms directly bonded to Pt can be calculated well only within the framework of the fully relativistic matrix Dirac-Kohn-Sham (mDKS) level ( = 0.9973, = 3.
View Article and Find Full Text PDFNat Commun
January 2025
NASA Goddard Space Flight Center, Heliophysics Science Division, Greenbelt, MD, USA.
Shock waves, the interface of supersonic and subsonic plasma flows, are the primary region for charged particle acceleration in multiple space plasma systems, including Earth's bow shock, which is readily accessible for in-situ measurements. Spacecraft frequently observe relativistic electron populations within this region, characterized by energy levels surpassing those of solar wind electrons by a factor of 10,000 or more. However, mechanisms of such strong acceleration remain elusive.
View Article and Find Full Text PDFNat Commun
January 2025
Département de Physique Appliquée, Université de Genève, Genève, Switzerland.
Non-signalling conditions encode minimal requirements that any (quantum) systems must satisfy in order to be consistent with special relativity. Recent works have argued that in scenarios involving more than two parties, correlations compatible with relativistic causality do not have to satisfy all possible non-signalling conditions but only a subset of them. Here we show that correlations satisfying only this subset of constraints have to satisfy highly non-local monogamy relations between the effects of space-like separated random variables.
View Article and Find Full Text PDFPhilos Trans A Math Phys Eng Sci
December 2024
School of Physics, Engineering and Technology, University of York, England, YO10 5DD, UK.
Multipolar quantum optics deals with the interaction of light with matter as a many-body bound system of charged particles where the coupling to electromagnetic fields is in terms of the multipolar electric polarization and magnetization. We describe two transformations applied to the conventional non-relativistic formalism, namely a gauge transformation applied directly to the fields at the Lagrangian stage and a unitary transformation applied to the old Hamiltonian. We show how such transformations lead to the same Power-Zienau-Woolley (PZW) formulation of the quantum electrodynamics (QED) of an overall electrically neutral many-body bound system of charges, including the internal motion as well as the gross dynamics of the centre of mass.
View Article and Find Full Text PDFCommun Phys
December 2024
C. N. Yang Institute for Theoretical Physics, Stony Brook University, Stony Brook, NY 11794 USA.
Solid-state detectors with a low energy threshold have several applications, including searches of non-relativistic halo dark-matter particles with sub-GeV masses. When searching for relativistic, beyond-the-Standard-Model particles with enhanced cross sections for small energy transfers, a small detector with a low energy threshold may have better sensitivity than a larger detector with a higher energy threshold. In this paper, we calculate the low-energy ionization spectrum from high-velocity particles scattering in a dielectric material.
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