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Exploring nonadiabatic effects by recoil of fast photoelectrons.

Phys Rev Lett

September 2009

Theoretische Chemie, Universität Heidelberg, D-69120 Heidelberg, Germany.

The recoil momentum imparted on the residual ion by the emission of a fast photoelectron gives rise to internal excitations of the ion. Because of this recoil, the photoionization transition is not a vertical one. By varying the photon energy and/or orientation of the system one can systematically create nuclear wave packets with different initial locations and momenta in nuclear space and thus explore nonadiabatic effects.

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