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http://dx.doi.org/10.1103/physreva.40.5052 | DOI Listing |
Nat Commun
January 2025
State Key Laboratory of Precision Spectroscopy, East China Normal University, Shanghai, China.
Partial wave analysis is key to interpretation of the photoionization of atoms and molecules on the attosecond timescale. Here we propose a heterodyne analysis approach, based on the delay-resolved anisotropy parameters to reveal the role played by high-order partial waves during photoionization. This extends the Reconstruction of Attosecond Beating By Interference of Two-photon Transitions technique into the few-photon regime.
View Article and Find Full Text PDFJ Phys Chem A
December 2024
Radboud University Nijmegen, Institute for Molecules and Materials, Heijendaalseweg 135, 6525 AJ Nijmegen, The Netherlands.
In molecular beam scattering experiments, an important technique for measuring product energy and angular distributions is velocity map imaging following photoionization of one or more scattered species. For studies with cold molecular beams, the ultimate resolution of such a study is often limited by the product detection process. When state-selective ionization detection is used, excess energy from the ionization step can transfer to kinetic energy in the target molecular ion-electron pair, resulting in measurable cation recoil.
View Article and Find Full Text PDFJ Chem Theory Comput
December 2024
Departamento de Química, Universidad Autónoma de Madrid, 28049 Madrid, Spain.
In this work, the two-center Dirac equation is solved numerically using an extension of an adapted B-spline basis set method previously implemented in relativistic atomic calculations (Fischer, C. F.; Zatsarinny, O.
View Article and Find Full Text PDFTalanta
January 2025
State Key Laboratory of Medical Proteomics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, 116023, People's Republic of China; Liaoning Key Laboratory for Mass Spectrometry Technology and Instrumentation, Dalian, 116023, People's Republic of China. Electronic address:
The escalating need for prompt and highly sensitive on-site detection of trace-level drugs is fueling the advancement of miniature, high-performance mass spectrometers and analytical methodologies. In this study, a miniature continuous atmospheric pressure interfaced ion trap mass spectrometer integrated with thermal desorption acetone-assisted photoionization (TD-CAPI-ITMS) was developed for highly sensitive detection of nonvolatile drugs in saliva and blood. By strategically extending the sampling time of the TD-CAPI-ITMS to cover the entire desorption process, a remarkable two-order-of-magnitude enhancement in the signal intensity of individual drugs was observed.
View Article and Find Full Text PDFSci Rep
August 2024
Department of Physics, National Tsing Hua University, Hsinchu, 30013, Taiwan.
We present a practical scheme for the efficient preparation of laser-cooled Ca ions in an ion trap. Our approach integrates two well-established methods: isotope-selective photoionization and isotope-specific parametric excitation. Drawing inspiration from the individual merits of each method, we have successfully integrated these techniques to prepare extended chains of Ca ions, overcoming the challenge posed by their low natural abundance of 0.
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