On the basis of anomalous isotopic compositions of oxygen and magnesium, 14 oxide grains from two primitive meteorites (Bishunpur and Semarkona) have been identified as circumstellar condensates. One corundum grain has a high 18O/16O ratio and isotopic compositions of magnesium, calcium, and titanium that are compatible with a formation in ejecta of a type II supernova that was about 15 times the mass of the sun. The other grains have oxygen, magnesium, and titanium compositions that are consistent with a formation around asymptotic giant branch (AGB) stars with a range of mass and initial composition. The large range of aluminum/magnesium in circumstellar corundum and spinel is considered to reflect various stages of back-reaction between condensed corundum and gaseous magnesium in cooling stellar ejecta.
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http://dx.doi.org/10.1126/science.282.5392.1284 | DOI Listing |
Chemosphere
December 2024
Department of Materials Science and Engineering, İzmir Institute of Technology, 35430, Gülbahçe, Urla, İzmir, Turkey. Electronic address:
The selective extraction of lithium from aqueous systems necessitates efficient sorbent materials. Spinel-type lithium manganese oxide ion sieves (LMOs) have been bee recognized for their high performance in this application. However, the elevated market cost of the spinel form (λ-MnO) raises economic concerns, posing challenges to the feasibility of the extraction process.
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November 2024
Cellulose and Paper Department, National Research Centre, 33 El-Bohouth Str., Dokki, P.O. 12622, Giza, Egypt.
ZnAlO and CuAlO spinel nanoparticles were prepared by a modified Pechini method and used with the natural chitosan (CS) and shellac (SH) polymers to form novel composite membranes as promising food packaging materials. The selection of ZnAlO and CuAlOspinel nanoparticles was based on their antibacterial characteristics, availability, and economy. Using a straightforward and adaptable solution mixing and casting method, the bio-composites were created.
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November 2024
Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeon, 34129, Republic of Korea; University of Science and Technology, 217 Gajeong-ro, Yuseong-gu, Daejeon, 34113, Republic of Korea. Electronic address:
The recent development of NH as a fuel has led to significant emissions of NO, a major greenhouse gas. Direct catalytic NO decomposition (de-NO) is a promising technology for NO emissions control because it effectively decomposes NO at low temperatures without requiring reducing agents or producing other pollutants. In marine applications, to improve the flame properties, NH is often mixed with marine diesel oil, which contains sulfur.
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October 2024
Electron Microscopy and Thin Films Department, National Research Centre, Dokki, Cairo, Egypt.
The possibility of reusing ceramic roller waste to produce cordierite and mullite refractories was investigated. Five batches were designed using wastes representing ceramic roller waste, magnesite, and silica sand, shaped and fired at 1300 °C/2 h, and one batch was selected at 1200 °C. The chemical composition and precipitated phases of the used raw materials and the fired batches were analyzed using XRF and XRD techniques, respectively.
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August 2024
Artificial Intelligence Laboratory for Mechanical and Civil Structures and Soil, University Center of Naama, Naama, Algeria.
Investigating novel compounds has become necessary due to the need for sophisticated materials in optoelectronic devices and spintronics. Because of their unique properties, magnesium-based spinels MgSm2X4 (X = S and Se) are very promising for these applications. We used the spin-polarized PBEsol for structural properties and the PBEsol functional for mechanical behavior, both using the WIEN2k code.
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