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Stabilization of Alkyltin γ-Keggin Clusters by 2, 5-Dihydroxyterephthalate Ligands.
Chem Asian J
January 2025
China Three Gorges University, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, College of Materials and Chemical Engineering, China Three Gorges University, CHINA.
The Keggin clusters are one kind of the most representative molecular structures in the field of metal-oxo clusters. Although the different types of Keggin clusters with various components were reported, the research about γ-Keggin isomer remains less developed. This is ascribed to the difficulty in obtaining the stable pure γ-Keggin cluster for the structural isomerization.
View Article and Find Full Text PDFAltered neurovascular coupling and structure-function coupling in Moyamoya disease affect postoperative collateral formation.
Sci Rep
December 2024
Department of Neurosurgery, The Second Affiliated Hospital, Zhejiang University School of Medicine, Jiefang Road 88th, Hangzhou, 310009, China.
Chronic ischemia in moyamoya disease (MMD) impaired white matter microstructure and neural functional network. However, the coupling between cerebral blood flow (CBF) and functional connectivity and the association between structural and functional network are largely unknown. 38 MMD patients and 20 sex/age-matched healthy controls (HC) were included for T1-weighted imaging, arterial spin labeling imaging, resting-state functional MRI and diffusion tensor imaging.
View Article and Find Full Text PDFCharacterization of Endofungal Bacteria and Their Role in the Ectomycorrhizal Fungus .
J Fungi (Basel)
December 2024
State Key Laboratory of Mycology, Institute of Microbiology, Chinese Academy of Sciences, Beijing 100101, China.
, an ectomycorrhizal fungus, forms a symbiotic relationship with , a rare and endangered species crucial to desert riparian ecosystems. In this study, endofungal bacteria (EFBs) within the fruiting bodies of were confirmed by a polyphasic approach, including genomic sequencing, real-time quantitative PCR targeting the 16S rRNA gene, full-length and next-generation sequencing (NGS) of the 16S rRNA gene, and culture methods. The genera , , , and were abundant in the EFBs of fruiting bodies associated with three hosts and were consistently present across different developmental stages.
View Article and Find Full Text PDFUnveiling the versatility of the thioredoxin framework: Insights from the structural examination of DsbA1.
Comput Struct Biotechnol J
December 2024
Department of Biochemistry and Chemistry, La Trobe Institute for Molecular Science, School of Agriculture, Biomedicine and Environment, La Trobe University, Bundoora, Australia.
In bacteria the formation of disulphide bonds is facilitated by a family of enzymes known as the disulphide bond forming (Dsb) proteins, which, despite low sequence homology, belong to the thioredoxin (TRX) superfamily. Among these enzymes is the disulphide bond-forming protein A (DsbA); a periplasmic thiol oxidase responsible for catalysing the oxidative folding of numerous cell envelope and secreted proteins. Pathogenic bacteria often contain diverse Dsb proteins with distinct functionalities commonly associated with pathogenesis.
View Article and Find Full Text PDF[Effects of Different Modified Corn Straw Biochar on Soil Hydraulic Properties in Hilly Loess Areas].
Huan Jing Ke Xue
November 2024
College of Resources and Environment, Shanxi Agricultural University, Taigu 030800, China.
Article Synopsis
- The study examines how modified corn straw biochar impacts water-related soil properties by preparing biochar through pyrolysis and modifying it with specific solvents.
- Various tests were conducted to analyze soil hydraulic conductivity, water evaporation, and moisture content using different concentrations and amounts of biochar.
- Results indicated that adding modified biochar significantly reduced soil hydraulic conductivity, improved water retention, and affected evaporation rates, providing insights for enhancing soil water retention in arid regions.
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