Temperature Dependence of Air-Broadening and Shift Coefficients of O3 Lines in the nu1 Band.

J Mol Spectrosc

Atmospheric Sciences Division, NASA Langley Research Center, Hampton, Virginia, 23681-0001

Published: April 1997

High-resolution Fourier transform absorption spectra of ozone broadened by dry air have been recorded at a number of temperatures from -63°C to 29°C. Using a multispectrum nonlinear least-squares procedure, we fit 29 of these spectra simultaneously to determine the air-broadening and shift coefficients and their temperature dependences for 450 lines in the 9-&mgr;m region; most of these belong to the nu1 band. Partial air-broadening results were obtained for 104 additional lines, and room-temperature self-broadening coefficients were also determined for most of the 554 lines measured. These results cover a wide range of rotational quantum numbers, particularly in the R branch, with J"

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http://dx.doi.org/10.1006/jmsp.1996.7232DOI Listing

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