Investigation of the Electrical Double Layer in a Metal Oxide/Monovalent Electrolyte Solution System.

J Colloid Interface Sci

Faculty of Chemistry, Maria Curie Sklodowska University, Pl. M. Curie-Sklodowskiej 3, Lublin, 20-031, Poland

Published: March 1997

Adsorption of the monovalent cations Cs+ and Na+ from mixed solutions of NaCl and CsCl at the TiO2(anatase)/water interface was studied. Higher adsorption of Cs+ than Na+ was observed from solutions of similar electrolyte concentration. The surface ionization and complexation constants of surface hydroxyl groups were determined using potentiometric titration data. Results for the adsorption of Cs+ and Na+ from mixed electrolyte solutions showed that these ions adsorb at different distances from the metal oxide surface.

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http://dx.doi.org/10.1006/jcis.1996.4690DOI Listing

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