The giant extracellular hemoglobin of Lumbricus terrestris was investigated in the oxygenated, deoxygenated and reoxygenated state using small angle X-ray scattering. Scattering experiments of the oxygenated state of the protein yielded a radius of gyration of 10.71 +/- 0.02 nm, a maximum diameter of 29.37 +/- 0.21 nm and a volume of 6200 +/- 200 nm3. The values for the deoxygenated state of the hemoglobin are smaller than the values for the oxygenated state, but the differences hardly exceed the limits of error.
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http://dx.doi.org/10.1016/s0167-4838(96)00141-0 | DOI Listing |
Inorg Chem Front
December 2024
University of Innsbruck, Department of General, Inorganic and Theoretical Chemistry Innrain 80-82 6020 Innsbruck Austria
We report the synthesis of dianionic OCO-supported NHC and MIC complexes of molybdenum and tungsten with the general formula (OCO)MO (OCO = bis-phenolate benzimidazolylidene M = Mo (1-Mo), bis-phenolate triazolylidene M = Mo (2-Mo), M = W (2-W) and bis-phenolate imidazolylidene, M = Mo (3-Mo), W (3-W)). These complexes are tested in the catalytic deoxygenation of nitroarenes using pinacol as a sacrificial oxygen atom acceptor/reducing agent to examine the influence of the carbene and the metal centre in this transformation. The results show that the molybdenum-based triazolylidene complex 2-Mo is by far the most active catalyst, and TOFs of up to 270 h are observed, while the tungsten analogues are basically inactive.
View Article and Find Full Text PDFJ Vis Exp
January 2025
Department of Biomedical Engineering, Washington University in St. Louis; Department of Obstetrics & Gynecology, Washington University in St. Louis;
For noninvasive light-based physiological monitoring, optimal wavelengths of individual tissue components can be identified using absorption spectroscopy. However, because of the lack of sensitivity of hardware at longer wavelengths, absorption spectroscopy has typically been applied for wavelengths in the visible (VIS) and near-infrared (NIR) range from 400 to 1,000 nm. Hardware advancements in the short-wave infrared (SWIR) range have enabled investigators to explore wavelengths in the ~1,000 nm to 3,000 nm range in which fall characteristic absorption peaks for lipid, protein, and water.
View Article and Find Full Text PDFNat Commun
January 2025
School of Environmental and Chemical Engineering, Wuyi University, Jiangmen, PR China.
Developing efficient strategies for the deoxygenative functionalization of carbonyl compounds is crucial for enhancing the effective utilization of biomass and the upgrading of chemical feedstocks. In this study, we present an elegant cathodic reduction strategy that enables a tandem alkylation/dearomatization reaction between quinoline derivatives and aryl aldehydes/ketones in a one-pot process. Our approach can be executed via two distinct paths: the aluminum (Al)-facilitated spin-center shift (SCS) path and the Al-facilitated direct deoxygenation path.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Microbiology, Oregon State University, 220 Nash Hall, Corvallis, OR, USA.
Global oxygen minimum zones (OMZs) often reach hypoxia but seldom reach anoxia. Recently it was reported that Michaelis Menten constants (K) of oxidative enzymes are orders of magnitude higher than respiratory K values, and in the Hypoxic Barrier Hypothesis it was proposed that, in ecosystems experiencing falling oxygen, oxygenase enzyme activities become oxygen-limited long before respiration. We conducted a mesocosm experiment with a phytoplankton bloom as an organic carbon source and controlled dissolved oxygen (DO) concentrations in the dark to determine whether hypoxia slows carbon oxidation and oxygen decline.
View Article and Find Full Text PDFAdv Sci (Weinh)
January 2025
School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001, China.
The potential of hydrogen plasma arc technology for the efficient deoxygenation and recycling of titanium alloy scrap is explored. The results of thermodynamic analysis reveal that hydrogen plasma is suitable for oxygen removal. The intermediate stages of the deoxygenation process are sequentially analyzed, showing that the hydrogen plasma arc primarily facilitated the reduction and dissolution of oxides as well as eliminated interstitial oxygen.
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