Thiobacillus novellus was able to grow with oxalate, formate, formamide, and methanol as sole sources of carbon and energy. Extensive growth on methanol required yeast extract or vitamins. Glyoxylate carboligase was detected in extracts of oxalate-grown cells. Ribulose bisphosphate carboxylase was found in extracts of cells grown on formate, formamide, and thiosulfate. These data indicate that oxalate is utilized heterotrophically in the glycerate pathway, and formate and formamide are utilized autotrophically in the ribulose bisphosphate pathway. Nicotinamide adenine dinucleotide-linked formate dehydrogenase was present in extracts of oxalate-, formate-, formamide-, and methanol-grown cells but was absent in thiosulfate- and acetate-grown cells.
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http://dx.doi.org/10.1128/jb.131.2.389-398.1977 | DOI Listing |
J Environ Sci (China)
July 2025
State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China; University of Chinese Academy of Sciences, Beijing 100049, China. Electronic address:
Formamide condensation with Ni can generate the NC structure, widely recognized as an efficient catalyst for electrocatalytic CO reduction reaction (CORR). To improve the utilization efficiency of Ni atoms, we introduced metal oxides as substrates to modulate the growth of a formamide-Ni (FA-Ni) condensate. FA-Ni@TiO demonstrated 2.
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December 2024
Max Planck Institute for Marine Microbiology, Celsiusstraße 1, 28359 Bremen, Germany.
Chemosphere
November 2024
Institute of Environmental Engineering, National Sun Yat-sen University, Taiwan.
High-strength wastewater containing elevated levels of chloride salt and N, N-dimethylformamide (DMF) solvent was collected from manufacturing of sunscreen cream (for UVA/UVB protection) at a cosmetic factory. In evaporation process, precipitates, formed due to the high chloride content (around 160 g/L), clog the pipeline, seriously reducing the treatment efficiency. This study aimed to develop a two-stage process integrating chemical precipitation and electrochemical oxidation to specifically remove the concentrated chloride salt and organic compounds (COD >100 g/L).
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Guangxi Key Laboratory of Environmental Processes and Remediation in Ecologically Fragile Regions (Guangxi Normal University), 15 Yucai Road, 541004, PR China.
This study demonstrated the effects of the sludge type and inoculation method on the N,N-dimethylformamide degradation pathway and associated microbial communities. The sludge type is critical for DMF metabolism, with acclimatized aerobic sludge having a significant advantage in terms of DMF metabolism performance, whereas acclimatized anaerobic sludge has a reduced DMF metabolism capacity. Metagenomic revealed increased abundances of Methanosarcina, Pelomona and Xanthobacter in the adapted anaerobic sludge, suggesting that anaerobic sludge can utilize the methyl products produced by DMF metabolism for growth.
View Article and Find Full Text PDFDalton Trans
November 2024
Department of Chemistry, Faculty of Science and Engineering, Swansea University, Swansea, UK.
Ruthenium(II) polypyridyl complexes (RPCs) that emit from triplet metal-to-ligand charge transfer (MLCT) states find a wide variety of uses ranging from luminophores to potential anti-cancer or anti-bacterial therapeutics. Herein we describe a greener, microwave-assisted synthetic pathway for the preparation of homoleptic [Ru(N^N)] and bis-heteroleptic [Ru(N^N)(N'^N')] type complexes. This employs the bio-renewable solvent Cyrene™, dihydrolevoglucosenone, as a green alternative to ,'-dimethylformamide (DMF) in the synthesis of Ru(N^N)Cl intermediate complexes, obtaining comparable yields for N^N = 2,2'-bipyridine, 1,10-phenanthroline and methylated derivatives.
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