Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/jo00428a004 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Facile, Reversible Hydrogen Activation by Low-Coordinate Magnesium Oxide Complexes.
J Am Chem Soc
January 2025
EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews KY16 9ST, U.K.
New approaches to achieve facile and reversible dihydrogen activation are of importance for synthesis, catalysis, and hydrogen storage. Here we show that low-coordinate magnesium oxide complexes [{(nacnac)Mg}(μ-O)] , with nacnac = HC(RCNDip), Dip = 2,6-PrCH, R = Me (), Et (), Pr (), readily react with dihydrogen under mild conditions to afford mixed hydride-hydroxide complexes [{(nacnac)Mg}(μ-H)(μ-OH)] . Dehydrogenation of complexes is strongly dependent on remote ligand substitution and can be achieved by simple vacuum-degassing of (R = Pr) to regain .
View Article and Find Full Text PDFCorrigendum to 'Facile synthesis of flower-cluster ZIF nanocarriers: Performance in controlled release of thiamethoxam and insecticidal activity' [Environ. Res. 268 (2025) 120753].
Environ Res
January 2025
State Key Laboratory of Vegetable Biobreeding, Institute of Vegetables and Flowers, Chinese Academy of Agricultural Sciences, Key Laboratory of Vegetables Quality and Safety Control, Ministry of Agriculture and Rural Affairs of China, Beijing, 100081, China. Electronic address:
Guanine-Assisted Contrived Low Pt-Integrated MoC/C for Hydrogen Evolution Reaction.
Langmuir
January 2025
Materials Chemistry Department, CSIR-Institute of Minerals and Materials Technology, Bhubaneswar, Odisha 751013, India.
Due to the high cost of the available Pt electrocatalysts, the large-scale water electrolysis production of hydrogen has been hindered. Hydrogen generation via electrochemical water splitting is a renewable energy essential to a sustainable society, creating a distinct material interface that shows Pt-like properties with long-term stability crucial to hydrogen evolution reactions (HERs). Here, we synthesized the guanine-assisted facile synthesis of 1 wt % Pt/MoC/C having a layered type morphology via solid state calcined process followed by chemical reduction.
View Article and Find Full Text PDFIn situ generation of Copper sulfide within Poly(lactic-co-glycolic acid): A strategy for Safer photothermal therapy in Triple-Negative breast cancer.
Int J Pharm
January 2025
Department of Pharmacy, 900TH Hospital of Joint Logistics Support Force, Fuzhou 350025, China. Electronic address:
Copper sulfide nanoparticles (CuS NPs) have garnered significant attention in photothermal therapy (PTT) owing to their facile synthesis, biodegradability, stability, and excellent photothermal conversion efficiency. Nonetheless, their potential toxic effects have restricted their application. This research focuses on the encapsulation of CuS NPs with the biocompatible polymer poly(lactic-co-glycolic acid) (PLGA) to enhance their biocompatibility, thereby improving the efficacy and safety of PTT in the treatment of triple-negative breast cancer (TNBC).
View Article and Find Full Text PDFTransition Metal-Coordinated Polymer Achieves Stable Seawater Oxidation over NiFe Layered Double Hydroxide.
Inorg Chem
January 2025
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan, Shandong 250014, China.
Seawater electrolysis has emerged as a promising approach for the generation of hydrogen energy, but the production of deleterious chlorine derivatives (e.g., chloride and hypochlorite) presents a significant challenge due to the severe corrosion at the anode.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!