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The electrochemical oxidation of alcohol molecules has gained significance as a key anode reaction, offering an alternative to the oxygen evolution reaction (OER) for hydrogen (H) production and carbon dioxide (CO) reduction. The (photo)electrochemical oxidation of benzyl alcohol and its derivatives serves as an important model system, not only because benzyl alcohol oxidation is a critical industrial process, but also because it offers valuable insights into electrocatalytic biomass conversion. Tailoring this reaction through electrochemical and photoelectrochemical methods using heterogeneous noble and transition metal electrocatalysts presents a green approach and the potential for uncovering new reaction mechanisms.

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