The possible occurrence of loose gold and abutment screws retaining full-arch osseointegrated prostheses has been investigated. The prostheses had been in use for at least 5 years. The findings were related to clinical parameters such as accuracy of the superstructure, operator dependence, and clinical and radiological diagnosis of implant status after 5 years. The principles of the California Dental Association's (CDA) quality evaluation criteria were modified and applied in the study. Gold screw loosening was found to be related to framework misfit and was considered to be operator dependent to some extent. It is recommended that full-arch fixed prostheses be retightened after 5 years.
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Angew Chem Int Ed Engl
January 2025
Tsinghua University, Chemistry Department, 1 Tsinghua Yuan, Haidian District, 100084, Beijing, CHINA.
Open metal sites are crucial in catalysis. We have used a "loose coordination strategy" (LCS) to preorganize open metal sites in gold cluster catalysts. A gold nanocluster with composition of [Au26(3,4-Me2-Ph-form)9(iPr2-imy)3(Me2S)](BF4)2(iPr2-imy = 1,3-Diisopropylimidazolium tetrafluoroborate, 3,4-Me2-Ph-form = N,N'-Di(3,4-dimethyl-phenyl)formamidine) (Au26) has been obtained by one pot synthesis, i.
View Article and Find Full Text PDFInt J Mol Sci
December 2024
Department of Chemistry, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul 04763, Republic of Korea.
The effect of solution pH on the formation and surface structure of 2-pyrazinethiolate (2-PyzS) self-assembled monolayers (SAMs) formed by the adsorption of 2-mercaptopyrazine (2-PyzSH) on Au(111) was investigated using scanning tunneling microscopy (STM) and X-ray photoelectron microscopy (XPS). Molecular-scale STM observations clearly revealed that 2-PyzS SAMs at pH 2 had a short-range ordered phase of (2√3 × √21)R30° structure with a standing-up adsorption structure. However, 2-PyzS SAMs at pH 8 had a very unique long-range ordered phase, showing a "ladder-like molecular arrangement" with bright repeating rows.
View Article and Find Full Text PDFAm J Gastroenterol
December 2024
Faculty of Medicine and Health, University of Sydney, Camperdown, NSW.
Introduction: Defecatory disorders are common affecting up to 8% of the population. Rome IV diagnostic criteria are used to define this condition and therefore select patients for the gold standard therapy, anorectal biofeedback. The aim of this study was to test the current Rome IV FDD criteria in a real-world population by utilizing the response to biofeedback as a validation tool.
View Article and Find Full Text PDFJ Occup Health
December 2024
Griffith University School of Medicine and Dentistry and Gold Coast University Hospital, Southport, Queensland, Australia.
Objectives Pilonidal sinus is a recognized occupational condition sometimes seen in barbers and pet groomers, and it involves most commonly interdigital spaces. We present a previously unreported case of chronic paronychia with two separate digital pilonidal sinuses resulting from multiple embedded hair fragments in the eponychium of a dog groomer, who had been repeatedly treated with antibiotics with no success and ended up to surgical treatment. The objective of this study is to remind readers of this rare but possible occupational disease, particularly among employees working with hair, and to emphasize the importance of preventive measures to prevent its occurrence.
View Article and Find Full Text PDFMed Biol Eng Comput
November 2024
Department of Orthopedics, Balgrist University Hospital, University of Zurich, Zürich, Switzerland.
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