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Probing Interparticle Interaction and Ordering in Silica-Pluronic-Based Solutions and Emulsions by Small-Angle Scattering Techniques.
J Phys Chem B
January 2025
Homi Bhabha National Institute, Anushakti Nagar, Mumbai 400094, India.
Introduction of non-DLVO forces by nonionic surfactants brings about fascinating changes in the phase behavior of silica nanosuspensions. We show here that alterations in the interaction and wetting properties of negatively charged silica nanoparticles (Ludox® LS) in the presence of polyethylene oxide-polypropylene oxide-polyethylene oxide-based triblock copolymers called Pluronics lead to the formation of stable o/w Pickering emulsions and interparticle attraction-induced thermoresponsive liquid-liquid phase separations. The results make interesting comparisons with those reported for Ludox® TM nanosuspensions comprising larger silica nanoparticles.
View Article and Find Full Text PDFImpact of liquid-liquid phase separation- and immune-related gene signatures on multiple myeloma prognosis: focus on DDX21 and EZH2.
Hematology
December 2025
Department of Hematology, Shaoxing Shangyu people's Hospital, Shaoxing, People's Republic of China.
Objective: Liquid-liquid phase separation (LLPS) may affect the therapeutic sensitivity of multiple myeloma (MM). This study aimed to identify LLPS-related genes with MM prognostic values and to confirm their effects on tumor progression.
Methods: Based on public transcriptomic data, this study screened LLPS- and immune-related genes for MM-derived plasma cells.
Application and Output Performance Comparison of Janus and Traditional Transition Metal Chalcogenides in Ytterbium-Doped Fiber Lasers.
ACS Appl Mater Interfaces
January 2025
College of Automation, Xi'an University of Posts and Telecommunications, Xi'an 710100, China.
Janus transition metal disulfide (TMD) monolayers have two distinct carbon surfaces that break the inherent ground external mirror symmetry. When compared to traditional TMD materials, Janus TMDs not only inherit the advantages of traditional TMDs but also have new characteristics that are different from those of traditional TMDs. This paper describes the development of a stable passive Q-switched ytterbium-doped fiber laser (YDFL) with operating wavelengths of 1032.
View Article and Find Full Text PDFAutomated Systems with Fluorescence Detection for Metal Determination: A Review.
Molecules
December 2024
Department of Analytical Chemistry, Institute of Chemistry, Faculty of Science, Pavol Jozef Safarik University in Kosice, Moyzesova 11, 040 01 Kosice, Slovakia.
Industrialization has led to environmental pollution with various hazardous chemicals including pollution with metals. In this regard, the development of highly efficient analytical methods for their determination has received considerable attention to ensure public safety. Currently, scientists are paying more and more attention to the automation of analytical methods, since it permits fast, accurate, and sensitive analysis with minimal exposure of analysts to hazardous substances.
View Article and Find Full Text PDFOn the prediction by density functional theory of entropies in solution within implicit solvation models.
J Mol Model
December 2024
Normandy Univ., COBRA UMR 6014 & FR 3038, Université de Rouen, INSA Rouen, CNRS, 1 rue Tesnière, 76821, Mont St Aignan Cedex, France.
Context: Entropies are fundamental contributions to Gibbs energies that carry important chemical information, in particular when investigating reaction mechanisms. However, evaluating them in solution is far from being straightforward. In this paper, we focus on its evaluation within the framework of implicit solvation models.
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