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Interplay of Tetrel, Hydrogen, and Halogen Bonds in FGeOCl and HCN Complexes: A Comprehensive Theoretical Study of Dimers, Trimers, and Tetramers.
J Phys Chem A
January 2025
Department of Chemistry and Biochemistry, Shahrood Branch, Islamic Azad University, 36714 Shahrood, Iran.
This study investigates the nature and interplay of noncovalent interactions (NCIs)─tetrel bonds (TB), hydrogen bonds (HB), and halogen bonds (XB)─in molecular assemblies formed between trifluorogermyl hypochlorite (FGeOCl) and hydrogen cyanide (HCN). Using a combination of high-level computational methods, we explored the geometric, energetic, and electronic properties of dimers, trimers, and tetramers formed in different molar ratios of interacting reagents. Various analyses reveal a significant cooperativity between TB and HB, which mutually reinforce each other, while XB interactions are diminished in the presence of TB and HB.
View Article and Find Full Text PDFA Study of Radium Content and Radon Exhalation Rates in Soil Samples from Abi-Adi Town, Ethiopia, Using LR-115 Type-II.
Health Phys
January 2025
Ayder Comprehensive Specialized Hospital, Mekelle University, Tigray, Ethiopia.
In the present study, we are presenting the results of radium content, radon concentration, and radon exhalation rates (both mass and area) for 32 soil samples collected from different locations of Abi-Adi Town, Ethiopia, by using the sealed can technique containing a LR-115 Type-II plastic detector. The values of radium content from soil samples were found to vary from 35.26 Bq kg-1 to 101.
View Article and Find Full Text PDFJealousy or Abuse? Dispositional Mindfulness Helps Chinese College Students Understand and Save From Cyber Dating Abuse.
Psychol Rep
January 2025
Faculty of Psychology, Tianjin Normal University, Tianjin, China.
Technology advances lead to a high prevalence of cyber dating abuse among youth. Previous studies had demonstrated its detrimental outcomes and predictors, but neglected the characters in Eastern countries. Therefore, exploring the comprehensive mechanisms of cyber dating abuse in different cultures and mitigating it are necessary.
View Article and Find Full Text PDFUse of Electronic Health Records to Identify Factors Related to Skin Changes in Terminal Patients.
Adv Skin Wound Care
January 2025
Chia-Jung Chan, MS, RN, is Head Nurse, Taipei Medical University Hospital, Taipei, Taiwan. Yeu-Hui Chuang, PhD, RN, is Professor, School of Nursing, College of Nursing, Taipei Medical University, and Researcher, Research Center in Nursing Clinical Practice, Wan Fang Hospital, Taipei Medical University; Tsai-Wei Huang, PhD, RN, is Professor, School of Nursing, College of Nursing. Taipei Medical University, and Researcher, Research Center in Nursing Clinical Practice, Wan Fang Hospital, Taipei Medical University; Made Satya Nugraha Gautama, S.Kep, Ns, is Lecturer, Department of Nursing, Faculty of Medicine, Universitas Pendidikan Ganesha, Bali, Indonesia.
Objective: To investigate the incidence of skin changes at life's end (SCALE) among hospice patients and identify associated factors.
Methods: The authors conducted a retrospective chart review of demographic data, medical history, Braden Scale assessment scores, Charlson Comorbidity Index, symptom records, and medical treatments of patients admitted to a local teaching hospital's hospice unit between May 2019 and April 2021.
Results: Most (79%) of the 300 hospice patients included in the study had cancer.
Preoperative Anxiety Management Practices in Pediatric Anesthesia: Comparative Analysis of an Online Survey Presented to Experts and Social Media Users.
JMIR Pediatr Parent
January 2025
Department of Anesthesiology, University Medical Center Goettingen, Goettingen, Germany.
Background: Managing preoperative anxiety in pediatric anesthesia is challenging, as it impacts patient cooperation and postoperative outcomes. Both pharmacological and nonpharmacological interventions are used to reduce children's anxiety levels. However, the optimal approach remains debated, with evidence-based guidelines still lacking.
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