The analysis of experimental and theoretical data for the dependence of the thermodynamic rigidity of the native DNA molecule on the ionic strength of solution has been fulfilled. It has been shown that in aqueous-salt solutions of DNA the statistical segment length (A) of the DNA molecule remains constant over the range of intermediate ionic strengths (mu > 0.002) and considerably increases over the range of small mu < 0.002. On the basis of viscosimetry and flowbirefringence measurements of aqueous-organic solutions of native DNA it has been hypothesized that the macromolecule's thermodynamic rigidity does not depend on the dielectric properties of the medium. In this connection it has been concluded that nonshielded Coulomb interactions between the nearest phosphate groups exert a stronger influence on the thermodynamic rigidity of the macromolecule as compared with Debye--Hückel interactions. The consideration of the hydrodynamical and optical data for aqueous organic DNA solutions of difinite ionic strength shows that the value of [n]/[eta] for DNA and consequently the optical anisotropy of the macromolecule remains constant irrespective of the presence of nonelectrolyte. On this basis it has been concluded that no appreciable alteration of the microform anisotropy occurs in all the systems under consideration.
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Acc Chem Res
January 2025
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.
ConspectusSymmetry is a pervasive phenomenon spanning diverse fields, from art and architecture to mathematics and science. In the scientific realms, symmetry reveals fundamental laws, while symmetry breaking─the collapse of certain symmetry─is the underlying cause of phenomena. Research on symmetry and symmetry breaking consistently provides valuable insights across disciplines, from parity violation in physics to the origin of homochirality in biology.
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Tianjin Key Laboratory of Food Science and Health, School of Medicine, NanKai University, Tianjin 300071, China. Electronic address:
Instant noodles are a worldwide food staple. However, the correlation between its production methods and nutritional characteristics remains unclear. This study aims to elucidate the effects of hydrothermal (steaming and boiling) and cooling techniques on instant noodles in-vitro digestibility.
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Department of Physical Medicine & Rehabilitation, New York University Langone Health, New York, NY, USA.
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School of Environmental and Chemical Engineering, Jiangsu Ocean University, Lianyungang 222000, PR China. Electronic address:
Metal-organic frameworks (MOFs) have shown significant potential in the photocatalytic activation of peroxydisulfate (PDS). Although many MOFs have been investigated for their ability to activate PDS, the impact of structural interpenetration on this process remains underexplored. In this study, MIL-88D(FeNi) and MIL-126(FeNi) were selected to systematically study this effect.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
Department of Chemistry and Bioscience, Kumoh National Institute of Technology, Gumi 39177, Republic of Korea.
Two porphyrin-based polymeric frameworks, SnP-BTC and SnP-BTB, as visible light photocatalysts for wastewater remediation were prepared by the solvothermal reaction of -dihydroxo-[5,15,10,20-tetrakis(phenyl)porphyrinato]tin(IV) (SnP) with 1,3,5-benzenetricarboxylic acid (HBTC) and 1,3,5-tris(4-carboxyphenyl)benzene (HBTB), respectively. The strong bond between the carboxylic acid group of HBTC and HBTB with the axial hydroxyl moiety of SnP leads to the formation of highly stable polymeric architectures. Incorporating the carboxylic acid group onto the surface of SnP changes the conformational frameworks as well as produces rigid structural transformation that includes permanent porosity, good thermodynamic stability, interesting morphology, and excellent photocatalytic degradation activity against AM dye and TC antibiotic under visible light irradiation.
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