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http://dx.doi.org/10.1016/0006-291x(81)91220-1 | DOI Listing |
The GSAG:Ce scintillator represents a promising and cost-effective alternative to the expensive GGAG:Ce. Recent studies have attributed its low light yield to the thermal quenching effect. In this study, we employed the strategy of adding an yttrium (Y) admixture to the GSAG matrix to increase the thermal activation energy of thermal quenching.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Key Laboratory of Advanced Marine Materials, 1219 Zhongguan West Road, 315201, Ningbo, CHINA.
Many marine organisms feature sensitive sensory-perceptual systems to sense the surrounding environment and respond to disturbance with intense bioluminescence. However, it remains a great challenge to develop artificial materials that can sense external disturbance and simultaneously activate intense luminescence, although such materials are attractive for visual sensing and intelligent displays. Herein, we present a new class of bioinspired smart gels constructed by integrating hydrophilic polymeric networks, metastable supersaturated salt and fluorophores containing heterogenic atoms.
View Article and Find Full Text PDFDalton Trans
January 2025
Yildiz Technical University, Faculty of Chemical and Metallurgical Engineering, Department of Metallurgical and Materials Engineering, Glass Research and Development Laboratory, Istanbul, 34220, Türkiye.
Elevated temperatures can lead to reabsorption and color drift, compromising the quality of phosphor-converted white light-emitting diode (pc-WLED) devices. To ensure the performance of WLEDs under these conditions, it is essential to develop luminescent materials that maintain stable color. Consequently, there is a pressing need for single-phase white-emitting phosphors with robust chromatic stability.
View Article and Find Full Text PDFMacromol Rapid Commun
January 2025
College of Chemistry, Key Laboratory of High Performance Plastics, Ministry of Education, Jilin University, Changchun, 130012, China.
Aggregation-induced emission (AIE) materials have gained significant attention for their unique fluorescence enhancement in the aggregated state. However, combining rigid polymers with AIE molecules to enhance luminescent properties remains to be investigated. In this work, two novel AIE-active polyarylethersulfone (PAES) derivatives are synthesized by incorporating tetraphenylethene (TPE) into either the side chain or main chain of PAES, resulting in side-chain polyarylethersulfone-tetraphenylethene (PAES-TPE) and main-chain polyarylethersulfone-tetraphenylethene (m-PAES-TPE), respectively.
View Article and Find Full Text PDFChem Asian J
January 2025
Universite de Rennes 1, Sciences Chimiques de Rennes - UMR 6226, Avenue du General Leclerc, Campus de Beaulieu, 35042, Rennes, FRANCE.
A novel coordination motif comprising [4]helicene fused with pyrazino-phenanthroline (H4PP) has been synthesized and reacted with ReCl(CO)5 to yield its rhenium(I) complex (Re-H4PP). Absorption and emission spectroscopic analysis conducted in dichloromethane and 2-methyltetrahydrofuran reveals that combining pyrazino-phenanthroline with helicene visibly affects the photophysical attributes of both the resulting ligand and its Re(I) complex as compared to their non-helicene analogues, and even more importantly leads to relatively high photoluminescence quantum yield values, especially in the case of H4PP (29%). Chiroptical studies through electronic circular dichroism and circularly polarized luminescence performed on enantiomerically enriched samples of Re-H4PP show the chiral nature of low-energy excited states affording notable glum values that amplify at cryogenic temperatures.
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