An electric discharge was made through a gas mixture of N2 (7 cm Hg), H2 (14 cm Hg) and CO2 (14 cm Hg) over an aqueous solution (100 ml, pH 7.6) of adenosine (0.02 M) and phosphate (0.2 M) in a 5 liter vessel simulating primitive earth conditions. AMP was produced at a constant rate in the solution, and the yield reached about 2% in two months.
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http://dx.doi.org/10.1007/BF00931388 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Key Laboratory of Intelligent Supramolecular Chemistry at the University of Yunnan Province, National and Local Joint Engineering Research Center for Green Preparation Technology of Biobased Materials, School of Chemistry & Environment, Yunnan Minzu University, Kunming 650500, P. R. China.
Developing efficient and recyclable iodine adsorbents is crucial for addressing radioactive iodine pollution. An imidazole cation-bridged pillar[5]arene polymer (P5-P5I) was synthesized via a salt formation reaction. P5-P5I exhibited a high iodine vapor capture capacity of 2130.
View Article and Find Full Text PDFNat Nanotechnol
January 2025
Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, MD, USA.
Room-temperature non-aqueous sodium metal batteries are viable candidates for cost-effective and safe electrochemical energy storage. However, they show low specific energy and poor cycle life as the use of conventional organic-based non-aqueous electrolyte solutions enables the formation of interphases that cannot prevent degradations at the positive and negative electrodes. Here, to promote the formation of inorganic NaF-rich interphases on both negative and positive electrodes, we propose the salt-in-presalt (SIPS) electrolyte formulation strategy.
View Article and Find Full Text PDFOrg Lett
January 2025
Faculty of Chemistry, University of Wrocław, Joliot-Curie 14 Street, 50-383 Wrocław, Poland.
Studies presenting visible-light-induced desulfurization of peptides containing a cysteine residue have been carried out. This transformation driven by light-emitting-diode-type light proceeds with high efficiency in an aqueous solution at room temperature and involves the use of a catalytic amount of photosensitizer, Rose Bengal. The procedure has been tested on model synthetic peptides, lysozyme C and α-crystallin, and successfully applied to a one-pot native chemical ligation (NCL)-desulfurization protocol.
View Article and Find Full Text PDFEnviron Pollut
January 2025
Department of Civil and Environmental Engineering, Indian Institute of Technology Patna, Bihar - 801 106, India. Electronic address:
Perfluorooctanoic acid (PFOA) removal has gained significant attention due to its environmental stability and potential toxicity. This study aims to synthesize a chitosan-modified magnetic biochar (CS_MBC) for efficient PFOA removal from aqueous solutions. Various CS loading ratios (0.
View Article and Find Full Text PDFJ Environ Manage
January 2025
School of Environmental Science and Engineering, Changzhou University, Changzhou, 213164, PR China.
Compared with zero-valent iron, iron sulfide has more diverse reactive species and higher reductivity, but it is still prone to be gradually deactivated due to various passivation factors. In this study, a novel reductive material (BMMW@OA) was prepared by ball milling of mackinawite (MW) as raw material and oxalic acid (OA) as modifier, so as to simultaneously improve its reductivity and stability by continuous releasing reductive species and maintaining freshness of the material surface. The BMMW@OA (w/w of MW/OA = 4/1) effectively removed Cr(Ⅵ) from water with wide pH adaptability.
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