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Polymers (Basel)
November 2024
Elastomer Technology and Engineering (ETE), University of Twente, 7522 NB Enschede, The Netherlands.
In-rubber properties of vulcanizates deteriorate in the presence of incorporated recycled ground rubber (GR). This behavior is partly explained by a possible diffusion of sulfur from the rubber matrix into the GR. Therefore, the sulfur concentration and, thus, the crosslink density in the matrix are reduced.
View Article and Find Full Text PDFMaterials (Basel)
August 2024
Polymer Institute, Slovak Academy of Sciences, Dúbravská cesta 9, 845 41 Bratislava, Slovakia.
Polymers (Basel)
August 2024
Departamento de Fitoquímica, Facultad de Ciencias Naturales y Oceanográficas, Universidad de Concepción, Concepcion 3349001, Chile.
The forest industry produces several low-value by-products, such as bark, sawdust, limbs, and leaves, that are not ultimately disposed of and remain in the forests and sawmill facilities. Among these by-products are leaves, which contain not only cellulose fibers and lignin but also essential oils such as terpenes. These are biosynthesized in a similar way as cis-1,4-polyisoprene.
View Article and Find Full Text PDFLangmuir
June 2024
State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China.
The inclusion of sacrificial hydrogen bonds is crucial for advancing high-performance rubber materials. However, the molecular mechanisms governing the impact of these bonds on material properties remain unclear, hindering progress in advanced rubber material research. This study employed all-atom molecular dynamics simulations to thoroughly investigate how hydrogen bonds affect the structure, dynamics, mechanics, and linear viscoelasticity of rubber materials.
View Article and Find Full Text PDFInt J Biol Macromol
June 2024
College of Mechanical and Electronic Engineering, Northwest Agriculture & Forestry University, Yangling, Shaanxi 712100, China; Western Scientific Observation and Experiment Station for Development and Utilization of Rural Renewable Energy, M.O.A, Northwest Agriculture & Forestry University, Yangling, Shaanxi 712100, China. Electronic address:
Eucommia ulmoides rubber (EUR) is a high-quality natural rubber resource, which can be extracted from different organs of the Eucommia ulmoides tree. In this study, EUR was isolated from the leaves, barks, and pericarps, and the structural characteristics and physicochemical properties of EUR were systematically determined. The accumulation and distribution of EUR in different tissues were assessed through in situ observations combined with cellular and subcellular scales.
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