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Preparation of a 6FDA-DAM/ODA Mixed Matrix Membrane Doped with MOFs and Its Application in Gas Separation.

ACS Appl Mater Interfaces

January 2025

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, China.

Mixed matrix membranes (MMMs) can significantly improve gas separation performance, but the type and state of the filler in the membrane matrix are key indicators for the development of MMMs. Therefore, in this work, 6FDA-DAM/ODA (1:1), metal-organic frameworks (MOFs) with different particle sizes (UiO-66 and UiO-66-NH) were synthesized, and then MOFs were doped into 6FDA-DAM/ODA to prepare MMMs. The effects of the dopant materials and their particle sizes on the gas separation performance of the membranes were investigated by testing the permeability of the MMMs to H, CO, CH, and N.

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Given the inherent challenges of the CO electroreduction (COER) reaction, solely from CO and HO, it is desirable to develop selective product formation pathways. This can be achieved by designing multimetallic nanocomposites that provide optimal CO coverage, allowing for tunability in the product formation. In this work, Ag and Zn codoped-SrTiO (ZAST) composite immobilized carbon black (CB)-modified GCE working electrode (ZAST@CB/GCE) was developed for the electrochemical conversion of CO to multicarbon products.

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Fabrication of Hypoxia-Mimicking Supramolecular Hydrogels for Cartilage Repair.

ACS Appl Bio Mater

January 2025

Regenerative Medicine and Stem Cell Laboratory (RMS), Department of Biomedical Engineering, Indian Institute of Technology Hyderabad, Kandi 502 284, Telangana, India.

Despite advancements in chronic arthritis treatment, there remains a significant demand for advanced nanotechnologies capable of efficiently delivering a wide range of therapeutic agents to provide symptomatic relief and facilitate the healing of inflamed cartilage tissue. Considering the significant impact of hypoxia on the development and maintenance of chondral tissue, replicating its effects on stem cells could be a potential approach for the treatment of osteoarthritis (OA). Cobalt is a prominent hypoxia-inducing agent, owing to its ability to activate the hypoxia-inducible factor (HIF) pathway regardless of cellular oxygen levels.

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Deployment of large numbers of low capital cost sensors to increase the spatial density of air quality measurements enables applications that build on mapping air at neighborhood scales. Effective deployment requires not only low capital costs for observations but also a simultaneous reduction in labor costs. The Berkeley Environmental Air Quality and CO Network (BEACON) is a sensor network measuring O, CO, NO, and NO, particulate matter (PM), and CO at dozens of locations in cities where it is deployed.

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Constructing fecal-derived electrocatalysts for CO upcycling: simultaneously tackling waste and carbon emissions.

Nanoscale

January 2025

School of Chemistry and Chemical Engineering, School of the Environment, State Key Laboratory of Pollution Control & Resource Reuse, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China.

The escalating global fecal waste and rising CO levels present dual significant environmental challenges, further intensified by urbanization. Traditional fecal waste management methods are insufficient, particularly in addressing the related health risks and environmental threats. This study explores the synthesis of biochar from pig manure as a carbon substrate to disperse and stabilize Cu nanoparticles, resulting in the formation of an efficient Cu-NB-2000 electrocatalyst for electrocatalytic CO reduction (ECR).

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