Chemical conversion of trisaccharide d-Man beta 1----4-L-Rha alpha 1----3-D-[6-C-3H]Gal into its moraprenyl pyrophosphate derivative is described. Treatment of the latter with the cell envelope preparation from S. anatum results in the formation of polysaccharide with the alpha 1----6 linkage between the trisaccharide units.
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