Base ratio of DNA from 21 bacteriophage of Pseudomonas was determined by chemical hydrolysis and paper chromatography. Obtained values of the GC pair content were compared with melting temperature of DNA in 0,1 X SSC. The content of GC pairs correlates with melting temperature by equation %GC = 2,53 (Tm - 53,4). The content of GC pair for DNA from 30 bacteriophages of Pseudomonas was calculated. Some speculations concerning the distribution in DNA base ratio of bacteriophages of Pseudomonas are discussed.
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Inorg Chem
January 2025
Heterogeneous Catalysis, Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, Mülheim 45470, Germany.
Reductive phosphatization is an original synthesis approach to the formation of transition metal phosphates (TMPs). The approach enables the synthesis of known TMPs, but also new compounds, especially with transition metals in a low-valent state. However, to exploit the enormous potential of this synthesis method, it is necessary to identify and characterize all of the potential intermediates and final synthesis products.
View Article and Find Full Text PDFActa Crystallogr C Struct Chem
February 2025
Department Chemie, Ludwig-Maximilians Universität, Butenandtstrasse 5-13 (Haus D), D-81377 München, Germany.
Acyl fluorides and acyl cations represent typical reactive intermediates in organic reactions, such as Friedel-Crafts acylation. However, the comparatively stable phenyl-substituted compounds have not been fully characterized yet, offering a promising backbone. Attempts to isolate the benzoacylium cation have only been carried out starting from the acyl chloride with weaker chloride-based Lewis acids.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
Sino-French Hoffmann Institute, School of Basic Medical Science, Guangzhou Medical University, Guangzhou 511436, China.
A transparent fluoroborosilicate glass ceramic was designed for the controllable precipitation of fluoride nanocrystals and to greatly enhance the photoluminescence of active ions. Through the introduction of BO into fluorosilicate glass, the melting temperature was decreased from 1400 to 1050 °C, and the abnormal crystallization in the fabrication process of fluorosilicate glass was avoided. More importantly, the controlled crystallizations of KZnF and KYbF in fluoroborosilicate glass ceramics enhanced the emission of Mn and Mn-Yb dimers by 6.
View Article and Find Full Text PDFJ Funct Biomater
January 2025
Department of Chemistry, Sapienza University of Rome, P.le Aldo Moro 5, 00185 Rome, Italy.
Polymeric materials made from renewable sources that can biodegrade in the environment are attracting considerable attention as substitutes for petroleum-based polymers in many fields, including additive manufacturing and, in particular, Fused Deposition Modelling (FDM). Among the others, poly(hydroxyalkanoates) (PHAs) hold significant potential as candidates for FDM since they meet the sustainability and biodegradability standards mentioned above. However, the most utilised PHA, consisting of the poly(hydroxybutyrate) (PHB) homopolymer, has a high degree of crystallinity and low thermal stability near the melting point.
View Article and Find Full Text PDFMar Drugs
December 2024
Division of Aquaculture, Upgrading and Bioprospection, Portuguese Institute for the Sea and Atmosphere (IPMA, I.P.), Av. Doutor Alfredo Magalhães Ramalho 6, 1495-165 Algés, Portugal.
Co-products from the frozen fish processing industry often lead to financial losses. Therefore, it is essential to transform these co-products into profitable goods. This study explores the production of fish protein hydrolysates (FPH) from three co-products: the heads and bones of black scabbardfish (), the carcasses of gilthead seabream (), and the trimmings of Nile perch ().
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