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Determination of zinc complexation with an immobilized reagent for the analysis of environmental objects.
Talanta
January 2025
National University of Uzbekistan Named After Mirzo Ulugbek, Tashkent, 100174, Uzbekistan.
Although significant progress has been made in the effective measurement of Zn(II), Аlizarin red S (ARS) was immobilized on polyethylene polyamine-modified polyacrylonitrile (PPF-1) via a new matrix. This approach allows the detection of low levels of Zn(II) ions in various water samples via preconcentrated atomic absorption spectrometry. The use of PPF-1 in a polymer matrix for zinc preconcentration presents several advantages over traditional sorbtion-spectroscopic methods, including reduced cost, high zinc recovery, increased sensitivity, and selectivity.
View Article and Find Full Text PDFPreservation of organic carbon in marine sediments sustained by sorption and transformation processes.
Nat Geosci
January 2025
School of Earth and Environment, University of Leeds, Leeds, UK.
Controls on organic carbon preservation in marine sediments remain controversial but crucial for understanding past and future climate dynamics. Here we develop a conceptual-mathematical model to determine the key processes for the preservation of organic carbon. The model considers the major processes involved in the breakdown of organic carbon, including dissolved organic carbon hydrolysis, mixing, remineralization, mineral sorption and molecular transformation.
View Article and Find Full Text PDFA Cd-based crystalline network material: catalytic properties and post-synthetic metal-ion metathesis with enhanced stability and gas sorption behaviour.
Dalton Trans
January 2025
Department of Chemistry, Jadavpur University, Jadavpur, Kolkata-700 032, West Bengal, India.
This study presents the synthesis of a Cd(II) based hydrophobic three dimensional crystalline network material (CNM), [Cd(L)(LH)(bpe)], {L = {4,4'-(hexafluroisopropylidine)bis(benzoate)} and 1,2-di(4-pyridyl) ethylene (bpe)}, 1(Cd), by employing the slow-diffusion method. The three-dimensional structure of 1(Cd) was determined by single crystal X-ray diffraction and characterized by powder X-ray diffraction (PXRD), FT-IR spectroscopy and thermogravimetric analysis (TGA). Subsequently, post-synthetic modification of 1(Cd) with Cu(II) at room temperature led to the formation of isostructural 1(Cu) with partial substitution.
View Article and Find Full Text PDFAdjustment of Molecular Sorption Equilibrium on Catalyst Surface for Boosting Catalysis.
Acc Chem Res
January 2025
Key Lab of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China.
ConspectusFor chemical reactions with complex pathways, it is extremely difficult to adjust the catalytic performance. The previous strategies on this issue mainly focused on modifying the fine structures of the catalysts, including optimization of the geometric/electronic structure of the metal nanoparticles (NPs), regulation of the chemical composition/morphology of the supports, and/or adjustment of the metal-support interactions to modulate the reaction kinetics on the catalyst surface. Although significant advances have been achieved, the catalytic performance is still unsatisfactory.
View Article and Find Full Text PDFDevelopment of an antimicrobial tissue conditioner with quaternary ammonium methacryloxy silane (K18): An in vitro study.
J Prosthodont Res
January 2025
Department of Comprehensive Dentistry, UT Health San Antonio, San Antonio, USA.
Purpose: To determine the effects of K18 quaternary ammonium methacryloxy silane (QAS) on tissue conditioner materials and their antimicrobial properties.
Methods: 30% K18 QAS in methyl methacrylate (MMA; K18-MMA; 0%, 15%, and 20% w/w) was incorporated into a commercial tissue conditioner (Coe comfort). The degree of curing (Shore A hardness), hydrophilicity (contact angle), flow, liquid sorption, mass loss, and antimicrobial properties of Streptococcus mutans, Streptococcus sanguinis, and Candida albicans were determined.
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