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Crystalline Covalent Triazine Frameworks and 2D Triazine Polymers: Synthesis and Applications.

Acc Chem Res

January 2025

School of Engineering, Westlake University, Hangzhou 310024, Zhejiang Province, China.

ConspectusCovalent triazine frameworks (CTFs) are a novel class of nitrogen-rich conjugated porous organic materials constructed by robust and functional triazine linkages, which possess unique structures and excellent physicochemical properties. They have demonstrated broad application prospects in gas/molecular adsorption and separation, catalysis, energy conversion and storage, etc. In particular, crystalline CTFs with well-defined periodic molecular network structures and regular pore channels can maximize the utilization of the features of CTFs and promote a deep understanding of the structure-property relationship.

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-β, β-β' trifused porphyrins incorporating two distinct active methylene groups (MN = malononitrile and IND = 1,3-indanedione) and their corresponding metal complexes with Cu(II) and Zn(II) have been synthesized with good to excellent yields and characterized by various spectroscopic techniques and spectrometric methods. Single crystal X-ray analysis of the Zn(II) complex ZnTFPMB(MN) (where TFP = trifused porphyrin and MB = mono benzo) revealed a nonplanar 'armchair' type conformation with a twist angle of 24.10°.

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Today, cancer has become one of the leading global tragedies. It occurs when a small number of cells in the body mutate, causing some of them to evade the body's immune system and proliferate uncontrollably. Even more irritating is the fact that patients with cancers frequently relapse after conventional chemotherapy and radiotherapy, leading to additional suffering.

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Examining ozone effects on the tropical C crop .

PeerJ

January 2025

College of Science & Engineering and Centre for Tropical Environmental and Sustainability Science, James Cook University of North Queensland, Cairns, Queensland, Australia.

Ozone (O), a major air pollutant, can negatively impact plant growth and yield. While O impacts have been widely documented in crops such as wheat and soybean, few studies have looked at the effects of O on sorghum, a C plant and the fifth most important cereal crop worldwide. We exposed grain sorghum ( cv.

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Low fracture toughness, low-temperature degradation (LTD) susceptibility, and inadequate soft tissue integration greatly limit the application of zirconia ceramic abutment. Integrating the "surface" of hard all-ceramic materials into the gingival soft tissue and simultaneously promoting the "inner" LTD resistance and fracture toughness is challenging. Composite ceramics are effective in improving the comprehensive properties of materials.

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