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Recent Advancements of Bio-Derived Flame Retardants for Polymeric Materials.

Polymers (Basel)

January 2025

School of Mechanical and Manufacturing Engineering, University of New South Wales, Sydney, NSW 2052, Australia.

The sustainable flame retardancy of polymeric materials is a key focus for the direction of the next generation in the field of fire safety. Bio-derived flame retardants are gaining attention as environmentally friendly additives due to their low ecological impact and decreasing costs. These compounds can enhance char formation in polymeric materials by swelling upon heating, attributed to their functional groups.

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An Extensive Study of an Eco-Friendly Fireproofing Process of Lignocellulosic × Particles and Their Application in Flame-Retardant Panels.

Polymers (Basel)

January 2025

Laboratory of Physical Chemistry of Materials (LCPM), Campus Fanar, Faculty of Sciences II, Lebanese University, Fanar, Jdeidet P.O. Box 90656, Lebanon.

Increasing the flame retardancy of lignocellulosic materials such as × can effectively enable their wide use. This study examines the fireproofing process of Miscanthus particles using an eco-friendly process by grafting phytic acid and urea in aqueous solution. Miscanthus particles underwent a steam explosion step before being grafted.

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The interaction of sodium phytate hydrate CHOP·xNa·yHO (phytNa) with Cu(OAc)·HO and 1,10-phenanthroline (phen) led to the anionic tetranuclear complex [Cu(HO)(phen)(phyt)]·2Na·2NH·32HO (), the structure of the latter was determined by X-ray diffraction analysis. The phytate is completely deprotonated; six phosphate fragments (with atoms P1-P6) are characterized by different spatial arrangements relative to the cyclohexane ring (1a5e conformation), which determines two different types of coordination to the complexing agents-P1 and P3, P4, and P6 have monodentate, while P2 and P5 are bidentately bound to Cu cations. The molecular structure of the anion complex is stabilized by a set of strong intramolecular hydrogen bonds involving coordinated water molecules.

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Hybrid Modification of Wheat Bran Using Microbial Processing and Ultrasound: Enhancements in Bran Composition and Bread Quality.

Foods

January 2025

Food Engineering Department, Faculty of Chemical and Metallurgical Engineering, Yildiz Technical University, Davutpasa Campus, Istanbul 34220, Turkey.

This study investigates the effects of microbial bioprocessing (MB), ultrasound treatment (UT), and their combined application (hybrid method, HM) on the functional and nutritional enhancement of wheat bran (WB) and its impact on bread quality. MB was performed by using with LABE 32 (MB32) and LABE 29 (MB29). MB32 significantly increased soluble dietary fiber (SDF) and reduced phytic acid content by up to 25.

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Impact of surface conditioner phytic acid (IP6) Er,Cr:YSGG laser (ECYL) methylene blue photodynamic therapy (MB-PDT) on the microleakage and shear bond strength (SBS) of resin-modified glass ionomer cement (RMGIC) to primary sound dentin. Overall, 80 extracted sound primary molars were collected followed by their submergence in self-cure acrylic resin. The dentin surface was exposed and made flat and was assigned into four groups based on the surface conditioning.

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