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A Structurally Simple Polymer Donor Enables High-Efficiency Organic Solar Cells with Minimal Energy Losses.

Angew Chem Int Ed Engl

March 2025

South China University of Technology, State Key Laboratory of Luminescent Materials and Devices, Wushan Road 381, 510640, Guangzhou, CHINA.

Energy loss (Eloss) between optical energy gap (Eg) and open-circuit voltage (eVoc) sets efficiency upper limits for organic solar cells (OSCs). Nevertheless, further breaking the limit of Eloss in OSCs is challenging, especially via structurally simple materials in binary OSCs. Herein, a structurally simple non-halogenated polymer donor, namely PBDCT, is developed for realizing high-efficiency OSCs with record-breaking Eloss.

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Climate change, driven by greenhouse gas emissions, has emerged as a pressing global ecological and environmental challenge. Our study is dedicated to exploring the various factors influencing greenhouse gas emissions from animal husbandry and predicting their future trends. To this end, we have analyzed data from China's Inner Mongolia Autonomous Region spanning from 1978 to 2022, aiming to estimate the carbon emissions associated with animal husbandry in the region.

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Single-Atom Catalysts Boosted Electrochemiluminescence.

Chempluschem

March 2025

Shanghai University, Chemistry, Shangda Road 99, 200444, Shanghai, CHINA.

Electrochemiluminescence (ECL) combines electrochemical redox processes with photochemical light emission, offering exceptional sensitivity, spatial control, and stability. Widely applied in biosensing, medical diagnostics, and environmental monitoring, its efficiency often depends on advanced catalytic materials. Single-atom catalysts (SACs), featuring isolated metal atoms dispersed on a support, have emerged as promising candidates due to their unique electronic structures, high atom utilization, and tunable catalytic properties.

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Developing vapor-solid reaction methods to prepare organic-inorganic hybrid perovskite thin films is highly compatible with processes in crystalline silicon solar cells and the thin-film photovoltaic industries, facilitating rapid industrialization. In the vapor-solid reaction, the crystallization quality of perovskite thin films is widely influenced by the crystallinity and microstructure of lead iodide (PbI) precursor films. During the thermal evaporation process of preparing the PbI precursor films, we observed that PbI tends to develop a disordered surface morphology and exhibits high crystallinity, which significantly hinders the uniform diffusion of the organic amine salt vapor during the subsequent vapor-solid reaction.

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Incompatible electrode/electrolyte interface often leads to dendrite growth, parasitic reactions and corrosion, posing significant challenges to the application of Zn anodes. Herein, we introduce a biomimetic antifreeze protein localized gel electrolyte (ALGE) with multifunctional capabilities to address these issues by combining electrolyte modification with interface optimization. ALGE modifies the Zn2+ solvation structure and the hydrogen-bond network adjacent to zinc anode, effectively suppressing hydrogen evolution.

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