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Highly Porous Ionic Solids Consisting of AuCo Complex Anions and Aqua Metal Cations.
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Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
Article Synopsis
- Treatment of Na[AuCo(d-pen)] with M(OAc) in water results in ionic crystals with a highly porous 3D framework, featuring approximately 80% porosity due to hydrogen-bonding between anions and cations.
- Soaking these crystals leads to the formation of a 1D porous framework with about 60% porosity, where anions and cations are linked via coordination and hydrogen bonds.
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Fear learning depends on prediction error, or the discrepancy between the actual and expected outcome of a conditioning trial. These experiments used blocking and unblocking designs to study the role of opioid receptors in the nucleus accumbens (Acb) in predictive fear learning. Previous fear conditioning to a context blocked later fear conditioning to a conditioned stimulus (CS) in that context.
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