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Activated Nanocellulose from Corn Husk: Application to As and Pb Adsorption Kinetics in Batch Wastewater.

Polymers (Basel)

December 2024

Research Group for the Development of Advanced Materials for Water and Food Treatment, Universidad Nacional José María Arguedas, Andahuaylas 03701, Peru.

The aim of this study was to evaluate the removal of Pb and As from an aqueous solution using corn residue cellulose nanocrystals (NCCs). The corn husk was subjected to alkaline digestion, followed by bleaching and esterification with 3% citric acid to obtain NCCs. A 10 ppm multimetal solution of Pb and As was prepared.

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Impact of Citric Acid on the Structure, Barrier, and Tensile Properties of Esterified/Cross-Linked Potato Peel-Based Films and Coatings.

Polymers (Basel)

December 2024

Meat Technology & Science of Protein-Rich Foods (MTSP), Department of Microbial and Molecular Systems, Leuven Food Science and Nutrition Research Centre, KU Leuven Campus Ghent, B-9000 Ghent, Belgium.

The valorization of potato peel side streams for food packaging applications, especially for the substitution of current petrochemical-based oxygen barrier solutions such as EVOH, is becoming increasingly important. Therefore, potato peel-based films and coatings (on PLA) were developed containing 10-50% (/ potato peel) citric acid (CA). To determine the impact of CA concentration on the structure and physicochemical properties of cast films and coatings, ATR-FTIR spectroscopy, moisture adsorption isotherms, tensile properties, light transmittance, oxygen permeability, carbon dioxide transmission rate, and water vapor transmission rate measurements were performed.

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Investigating the Impact of Polymers on Clay Flocculation and Residual Oil Behaviour Using a 2.5D Model.

Polymers (Basel)

December 2024

Key Laboratory for Enhanced Oil & Gas Recovery of the Ministry of Education, Northeast Petroleum University, Daqing 163318, China.

In the process of oilfield development, the surfactant-polymer (SP) composite system has shown significant effects in enhancing oil recovery (EOR) due to its excellent interfacial activity and viscoelastic properties. However, with the continuous increase in the volume of composite flooding injection, a decline in injection-production capacity (I/P capacity) has been observed. Through the observation of frozen core slices, it was found that during the secondary composite flooding (SCF) process, a large amount of residual oil in the form of intergranular adsorption remained in the core pores.

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Novel Nanocomposites and Biopolymer-Based Nanocomposites for Hexavalent Chromium Removal from Aqueous Media.

Polymers (Basel)

December 2024

Department of Applied Chemistry and Engineering of Inorganic Compounds and the Environment, University Politehnica Timisoara, 2 Piata Victoriei, 300006 Timișoara, Romania.

Designing new engineered materials derived from waste is essential for effective environmental remediation and reducing anthropogenic pollution in our economy. This study introduces an innovative method for remediating metal-contaminated water, using two distinct waste types: one biowaste (eggshell) and one industrial waste (fly ash). We synthesized three novel, cost-effective nanoadsorbent types, including two new tertiary composites and two biopolymer-based composites (specifically k-carrageenan and chitosan), which targeted chromium removal from aqueous solutions.

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Density Functional Theory Insight in Photocatalytic Degradation of Dichlorvos Using Covalent Triazine Frameworks Modified by Various Oxygen-Containing Acid Groups.

Toxics

December 2024

Anhui Province Industrial Generic Technology Research Center for Alumics Materials, Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation, School of Physics and Electronic Information, Huaibei Normal University, Huaibei 235000, China.

Dichlorvos (2,2-dichlorovinyl dimethyl phosphate, DDVP) is a highly toxic organophosphorus insecticide, and its persistence in air, water, and soil poses potential threats to human health and ecosystems. Covalent triazine frameworks (CTFs), with their sufficient visible-light harvesting capacity, ameliorated charge separation, and exceptional redox ability, have emerged as promising candidates for the photocatalytic degradation of DDVP. Nevertheless, pure CTFs lack effective oxidative active sites, resulting in elevated reaction energy barriers during the photodegradation of DDVP.

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