Synthesis, Luminescent and Antibacterial Properties of Sol-Gel TiO/TeO/NbO Powders.

The present paper deals with the synthesis, characterization, and properties of sol-gel-derived TiO/TeO/NbO nanopowders. The gels were prepared using a combination of organic [Ti (IV) n-butoxide, Nb (V) ethoxide (CHNbO)] and inorganic [telluric acid (HTeO)] precursors. The aging of gels was performed in air for several days in order to enable further hydrolysis. The phase formation of the gels was investigated by XRD upon heating in the temperature range of 200-700 °C. It was established that the gels heat-treated up to 300 °C exhibited a predominantly amorphous phase in all binary and ternary compositions. The amount of amorphous phase gradually decreased with increasing temperature, and the first TiO (anatase) crystals were detected at about 400-500 °C. The average crystallite size of TiO (anatase) in the powdered samples heat-treated at 400 °C was about 10 nm. By DTA, it was established that the decomposition of organics is accompanied by strong weight loss occurring in the temperature range of 200-300 °C. The completeness of the hydrolysis-condensation reactions was verified by IR and UV-Vis analyses. The UV-Vis spectra of the as-prepared gels exhibited red shifting of the cut-off. Photoluminescence spectra exhibited a change in intensity with varying temperature and composition. The performed photocatalytic tests showed that all powders possess photocatalytic activity toward Malachite green organic dye. The obtained nanopowders exhibited good antibacterial properties against . The obtained samples can be considered as prospective materials for use as environmental catalysts.