Quantum computers hold the promise of solving certain problems that lie beyond the reach of conventional computers. Establishing this capability, especially for impactful and meaningful problems, remains a central challenge. Here we show that superconducting quantum annealing processors can rapidly generate samples in close agreement with solutions of the Schrödinger equation. We demonstrate area-law scaling of entanglement in the model quench dynamics of two-, three- and infinite-dimensional spin glasses, supporting the observed stretched-exponential scaling of effort for matrix-product-state approaches. We show that several leading approximate methods based on tensor networks and neural networks cannot achieve the same accuracy as the quantum annealer within a reasonable timeframe. Thus quantum annealers can answer questions of practical importance that may remain out of reach for classical computation.
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http://dx.doi.org/10.1126/science.ado6285 | DOI Listing |
J Am Chem Soc
March 2025
Department of Chemistry, University of California, Berkeley, Berkeley, California 94720, United States.
Metal halide perovskites have excellent optoelectronic properties. This study aims to determine how the optoelectronic properties of a model perovskite, cesium lead bromide (CsPbBr), change with length and thickness in one dimension (1D). By examining the photophysics of CsPbBr quantum dots (QDs), nanowires (NWs), and nanorods (NRs), we observe the influence of confinement, exciton diffusion, and trapping on their optical properties.
View Article and Find Full Text PDFJ Am Chem Soc
March 2025
Spin-X Institute, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 511442, China.
The electric control of magnetism has been considered to be promising for molecular spintronics and quantum information. However, the spin-electric coupling strength appears to be insufficient for application in most cases. Two major factors capable of amplifying the relative effect are spin-orbit coupling and ferroelectricity.
View Article and Find Full Text PDFAnesthesiology
March 2025
Professor of Anesthesiology and Perioperative Medicine, Department of Basic and Applied Medical Sciences, Ghent University, Ghent, Belgium; Professor, Department of Anesthesiology, UZLeuven, Leuven, Belgium & Department of Cardiovascular Sciences, KULeuven, Leuven, Belgium; Staff anesthesiologist, Department of Anesthesiology, OLV Hospital, Aalst, Belgium.
Background: The use of capturing devices may become required for the continued use desflurane. We tested the percentage of desflurane captured by a charcoal filter (CONTRAfluran)-workstation (Aisys) combination in vitro.
Methods: Desflurane in O2/air was administered via an Aisys workstation into a 2 L test lung that was insufflated with CO2 (160 mL/min).
Chempluschem
March 2025
Vrije Universiteit Amsterdam, Chemistry & Pharmaceutical Sciences, De Boelelaan 1083, 1081 HV, Amsterdam, NETHERLANDS, KINGDOM OF THE.
We have quantum chemically investigated the catalytic effect of hydrogen bonding organocatalysts, (H2N)2C=X (X = O, S, Se, NH, PH, AsH, CH2, SiH2 GeH2), such as urea, on the classic Diels-Alder reaction. All studied hydrogen bond donor catalysts enhance the Diels-Alder reaction between acrolein and 1,3-butadiene to a similar extent. Our activation strain and Kohn-Sham molecular orbital analyses show that these organocatalysts lower the reaction barrier by polarizing the p-orbitals away from the reactive carbon atoms of acrolein, reducing the Pauli repulsion between the reactants.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2025
School of Chemistry and Environment, Changchun University of Science and Technology, Changchun 130022, China.
Doping guest materials into host materials with a confined space to suppress nonradiative decay is an effective strategy for achieving room-temperature phosphorescence (RTP). However, constructing host-guest doped materials with ultralong RTP (URTP) is still challenging. Herein, by embedding three coumarin derivatives into boric acid via one-step heat treatment, the URTP material with an afterglow lasting up to 60 s, a phosphorescence lifetime of 1.
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