In recent years, halide perovskite materials have been extensively studied by researchers due to their excellent optoelectronic characteristics. Unlike traditional semiconductors, halide perovskites possess unique ionic crystal structures, which makes it easier to perform facile composition engineering to tailor their physical and chemical properties. Ion exchange is a popular post-treatment strategy to achieve composition engineering in perovskites, and various ion exchange processes have been used to modify the structural and functional features of prefabricated perovskites to meet the requirements of desired applications. This review summarizes the recent progress in ion exchange of halide perovskites, including mechanisms, strategies, and studies on different ion exchange. Additionally, the applications of ion-exchanged perovskites in microfluidic sensors, light-emitting diodes (LEDs), lasers, and solar cells are presented. Lastly, we briefly discuss the challenges in ion exchange of perovskites and hope that ion exchange can provide a more refined and reliable method for the preparation of high-performance perovskites.
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http://dx.doi.org/10.3390/nano15050375 | DOI Listing |
Nanomaterials (Basel)
February 2025
Institute of Polymer Optoelectronic Materials and Devices, Guangdong Basic Research Center of Excellence for Energy & Information Polymer Materials, State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates, South China University of Technology, Guangzhou 510640, China.
In recent years, halide perovskite materials have been extensively studied by researchers due to their excellent optoelectronic characteristics. Unlike traditional semiconductors, halide perovskites possess unique ionic crystal structures, which makes it easier to perform facile composition engineering to tailor their physical and chemical properties. Ion exchange is a popular post-treatment strategy to achieve composition engineering in perovskites, and various ion exchange processes have been used to modify the structural and functional features of prefabricated perovskites to meet the requirements of desired applications.
View Article and Find Full Text PDFNanomaterials (Basel)
February 2025
Facultad de Ciencias Básicas, Departamento de Física y Electrónica, Universidad de Córdoba, Monteria 230002, Colombia.
We investigated the hysteresis, pseudo-critical, and compensation behaviors of a quasi-spherical FeCo alloy nanoparticle (2 nm in diameter) using Monte Carlo simulations with thermal bath-type algorithms and a 3D mixed Ising model. The nanostructure was modeled in a body-centered cubic lattice (BCC) through the following configurations: spin S=3/2 for Co and Q=2 for Fe. These simulations reveal that, under the influence of crystal and magnetic fields, the nanoparticle exhibits compensation phenomena, exchange bias, and pseudo-critical temperatures.
View Article and Find Full Text PDFFront Chem
February 2025
South African Institute for Advanced Materials Chemistry, University of Western Cape, Cape Town, South Africa.
The conversion of carbon dioxide (CO), a major greenhouse gas, into light olefins is crucial for mitigating environmental impacts and utilizing non-petroleum-based feedstocks. Thermo-catalytic CO transformation into valuable chemicals offers a promising solution to this challenge. This study investigates the effect of potassium (K) and manganese (Mn) promoters on CO conversion and CH selectivity over CoFe-ZSM-5 zeolites.
View Article and Find Full Text PDFInorg Chem
March 2025
Chemistry and Bioengineering, Graduate School of Engineering, Osaka Metropolitan University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
A cyano-bridged coordination polymer (CP), K{Co[Fe(CN)]} {(K)}, insoluble in water was successfully solubilized by countercation exchange with MeN ions. On the one hand, the resultant powder remained insoluble after countercation exchange with NH or EtN ions. Powder X-ray diffraction measurements indicated that solubility was closely related to the crystal structures of the obtained powder after countercation exchange.
View Article and Find Full Text PDFInt J Biol Macromol
March 2025
School of Chemistry and Chemical Engineering, University of Jinan, 250022 Jinan, PR China. Electronic address:
Recovering bromide ions from wastewater can not only alleviate the shortage of bromine resources but also solve the problem of bromine pollution. However, there is no efficient method for selective extraction of bromide ions from bromine-containing wastewater up to now. In this paper, chitosan was acidified into a gel to extend its molecular chain, modified by quaternary ammonium salt functional groups, and then crosslinked to obtain a new adsorption material.
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