Controllable Preparation of Low-Cost Coal Gangue-Based SAPO-5 Molecular Sieve and Its Adsorption Performance for Heavy Metal Ions.

With the advancement of industrial production and urban modernization, pollution from heavy metal ions and the accumulation of solid waste have become critical global environmental challenges. Establishing an effective recycling system for solid waste and removing heavy metals from wastewater is essential. Coal gangue was used in this study as the primary material for the synthesis of a fully coal gangue-based phosphorus-silicon-aluminum (SAPO-5) molecular sieve through a hydrothermal process. The SAPO-5 molecular sieve was characterized through several methods, including X-ray diffraction (XRD), scanning electron microscopy (SEM), BET surface analysis, Fourier-transform infrared (FT-IR) spectroscopy, and X-ray photoelectron spectroscopy (XPS), to examine its mineral phases, microstructure, pore characteristics, and material structure. Adsorption performance towards wastewater with Cd and Pb ions was investigated. It was found that the adsorption processes of these ions are well described by both the pseudo-second-order model and the Langmuir isotherm. According to the Langmuir model, the coal gangue-based SAPO-5 molecular sieve exhibited maximum adsorption capacities of 93.63 mg·g for Cd and 157.73 mg·g for Pb. After five cycles, the SAPO-5 molecular sieve retained strong stability in adsorbing Cd and Pb, with residual adsorption capacities of 77.03 mg·g for Cd and 138.21 mg·g for Pb. The excellent adsorption performance of the fully solid waste coal gangue-based SAPO-5 molecular sieve is mainly attributed to its mesoporous channel effects, the complexation of -OH functional groups, and electrostatic attraction.