This study employs molecular dynamics simulations to unravel the interplay between twin spacing, temperature, and mechanical response in nanotwinned AgPd alloys. For fine-grained systems, a dual strengthening-softening transition emerges as twin spacing decreases, driven by a shift in dislocation behavior from inclined-to-twin-boundary slip to parallel-to-twin-boundary glide. In contrast, coarse-grained configurations exhibit monotonic strengthening with reduced twin spacing, governed by strain localization at grain boundaries and suppressed dislocation activity. Notably, cryogenic conditions stabilize pre-existing and nascent twins, whereas elevated temperatures intensify atomic mobility and boundary migration, accelerating twin boundary annihilation ("detwinning").
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http://dx.doi.org/10.3390/nano15050323 | DOI Listing |
Nanomaterials (Basel)
February 2025
School of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710072, China.
This study employs molecular dynamics simulations to unravel the interplay between twin spacing, temperature, and mechanical response in nanotwinned AgPd alloys. For fine-grained systems, a dual strengthening-softening transition emerges as twin spacing decreases, driven by a shift in dislocation behavior from inclined-to-twin-boundary slip to parallel-to-twin-boundary glide. In contrast, coarse-grained configurations exhibit monotonic strengthening with reduced twin spacing, governed by strain localization at grain boundaries and suppressed dislocation activity.
View Article and Find Full Text PDFACS Appl Mater Interfaces
February 2025
Department of Chemical Engineering and Materials Science, University of Minnesota-Twin Cities, Minneapolis, Minnesota 55455, United States.
Electrochemical doping of the n-type polymer poly(benzimidazobenzophenanthroline) (BBL) in contact with ionic liquids reveals a peak in the drain current () vs gate voltage () behavior, i.e., conductivity versus electron density.
View Article and Find Full Text PDFSci Rep
February 2025
School of Civil Engineering, Heilongjiang University, Harbin, 150080, China.
Wind-induced interference effects occur between high-rise twin buildings. To elucidate the impact of aerodynamic optimization measures on the interference effects between high-rise buildings, large eddy simulations (LES) were conducted to analyze the wind load characteristics of buildings with varying spacing. The simulation results were compared with experimental data and previous studies to validate the method's accuracy.
View Article and Find Full Text PDFLangmuir
March 2025
Department of Chemical Engineering, Indian Institute of Technology, Guwahati 781039, Assam, India.
Mater Horiz
January 2025
Department of Chemical Engineering, National Tsing Hua University, 101, Section 2, Kuang-Fu Road, Hsin-Chu 300044, Taiwan.
The formation of a high-density nanotwinned structure in copper deposits is presently acknowledged as a paramount goal for enhancing the material characteristics of copper. However, the conventional manufacturing processes often involve the incorporation of organic additives, resulting in consequential impurity effects and aging concerns. In this work, we introduce a high-rate approach to fabricate (220)-orientation nanotwinned copper foils in a concentrated methanesulfonate copper solution with mere amount of chloride ions as additives.
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