Since photocatalytic and electrocatalytic technologies are crucial for tackling the energy and environmental challenges, significant efforts have been put into exploring advanced catalysts. Among them, perovskite type ABO oxides show great promising catalytic activities because of their flexible physical and chemical properties. In this review, the fundamentals and recent progress in the synthesis of perovskite type ABO oxides are considered. We describe the mechanisms for electrocatalytic oxygen evolution reactions (OER), oxygen reduction reactions (ORR), hydrogen evolution reactions (HER), nitrogen reduction reactions (NRR), carbon dioxide reduction reactions (CORR), and metal-air batteries in details. Furthermore, the photocatalytic water splitting, CO conversion, pollutant degradation, and nitrogen fixation are reviewed as well. We also stress the applications of perovskite type ABO oxides in solid oxide fuel cells (SOFs). Finally, the optimization of perovskite type ABO oxides for applications in various fields and an outlook on the current and future challenges are depicted. The aim of this review is to present a broad overview of the recent advancements in the development of perovskite type ABO oxides-based catalysts and their applications in energy conversion and environmental remediation, as well as to present a roadmap for future development in these hot research areas.
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http://dx.doi.org/10.1021/acs.chemrev.4c00553 | DOI Listing |
ACS Sens
March 2025
Jiangsu Key Laboratory of New Drug Research and Clinical Pharmacy, Xuzhou Medical University, Xuzhou 221002, Jiangsu, China.
Traditional biological detection methods rely on signal amplification strategies such as enzymatic catalysis or nucleic acid amplification. However, their efficiency decreases in low-temperature environments, compromising their detection sensitivity. To break the loss of enzyme catalytic activity at low temperatures, research on cold-adaptive nanozymes has attracted much attention.
View Article and Find Full Text PDFChem Rev
March 2025
WA School of Mines: Minerals, Energy and Chemical Engineering (WASM-MECE), Curtin University, Perth, Western Australia 6102, Australia.
Since photocatalytic and electrocatalytic technologies are crucial for tackling the energy and environmental challenges, significant efforts have been put into exploring advanced catalysts. Among them, perovskite type ABO oxides show great promising catalytic activities because of their flexible physical and chemical properties. In this review, the fundamentals and recent progress in the synthesis of perovskite type ABO oxides are considered.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2025
CHOSE (Centre for Hybrid and Organic Solar Energy), Department of Electronic Engineering, Tor Vergata University of Rome, Via del Politecnico 1, Rome 00118, Italy.
Semitransparent perovskite solar cells (ST-PSCs) for tandem applications typically use a buffer layer deposited via atomic layer deposition (ALD) to protect the cell stack from the damage induced by the sputtering of the transparent electrode. Here, we present a simple yet effective solution-processed buffer layer based on metal-oxide nanoparticles to mitigate sputter-induced damage. We exploit this strategy in a monolithic tandem integrating the optimized ST-PSC on a polished front-side/unpolished rear-side -type silicon heterojunction (SHJ) solar cell.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2025
State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science, Fudan University, Shanghai 200433, P. R. China.
Perovskite has attracted extensive attention in the realm of photovoltaic and light-emitting diodes (LEDs) on account of its outstanding photoelectric properties. Perovskite-type quantum wells (QW) have been developed for high-efficiency perovskite-type LEDs. However, there are few reports on the in situ quantum well structure formed by a bimetallic antiperovskite and its properties.
View Article and Find Full Text PDFNanoscale
March 2025
Chemistry of Thin Film Materials, Department of Chemistry and Pharmacy, Friedrich-Alexander-Universität Erlangen-Nürnberg, Cauerstr. 3, 91058 Erlangen, Germany.
Perovskite oxides like barium titanate (BaTiO) exhibit desirable properties: notably high dielectric constants, piezoelectricity, and ferroelectricity, thereby enabling more advanced electronic devices and actuators. There are numerous synthesis procedures for BaTiO, among which, nanoparticle syntheses are versatile and well-studied. However, colloidal organometallic synthesis is less commonly employed for this material despite offering processing advantages like facile compositional control and customizable surface chemistry.
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