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Regulating the Crystallization and Morphology of PbI Precursor Films for the Growth of High-Quality Perovskite Films via Vapor-Solid Reaction.
ACS Appl Mater Interfaces
March 2025
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China.
Developing vapor-solid reaction methods to prepare organic-inorganic hybrid perovskite thin films is highly compatible with processes in crystalline silicon solar cells and the thin-film photovoltaic industries, facilitating rapid industrialization. In the vapor-solid reaction, the crystallization quality of perovskite thin films is widely influenced by the crystallinity and microstructure of lead iodide (PbI) precursor films. During the thermal evaporation process of preparing the PbI precursor films, we observed that PbI tends to develop a disordered surface morphology and exhibits high crystallinity, which significantly hinders the uniform diffusion of the organic amine salt vapor during the subsequent vapor-solid reaction.
View Article and Find Full Text PDFComprehensive evaluation of antibacterial and anticancer activities from indole butanoic acid.
J Genet Eng Biotechnol
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Department of Chemistry, College of Sciences, Jouf University, PO Box 72341, Sakaka, Saudi Arabia.
Focus of this study is on the use of the hydrazone compound (3) (N-(4-bromobenzylidene)-4-(1H-indol-3-yl) butane hydrazide), which was previously prepared from the reaction of the compound p-bromobenzaldehyde with the corresponding hydrazide (2), as an intermediate compound for the synthesis of azetidine, thiazolidine, tetrazole, oxadiazole and phthalazine heterocyclic compounds through its reaction with some cyclic reagents and catalysts such as chloro acetyl chloride, thioglycolic acid, sodium-azid, lead dioxide and Hydrogen chloride gas. The prepared compounds were characterized using physical properties and also spectroscopic methods such as infrared spectroscopy, nuclear magnetic resonance spectra of the proton and the isotope of carbon as well as mass spectrometry, which accurately identified the proposed structures of the prepared compounds. The identity of the prepared compounds was determined using physical and spectroscopic properties, where infrared and HNMR spectroscopy of the proton as well as carbon were used in addition to using mass spectrometry to verify the validity of the prepared structures.
View Article and Find Full Text PDFFunctional identification of mango MiGID1A and MiGID1B genes confers early flowering and stress tolerance.
Plant Sci
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State Key Laboratory for Conservation and Utilization of Subtropical Agro-Bioresources, Guangxi Key Laboratory for Agro-Environment and Agro-Product Safety, National Demonstration Center for Experimental Plant Science Education, College of Agriculture, Guangxi University, Nanning, 530004; Guangxi, China. Electronic address:
The GIBBERELLIN INSENSITIVE DWARF1 (GID1) gene encodes a receptor integral to Gibberellic acid (GA) signaling, which is pivotal for plant growth, development, and stress responses. Until now, GID1 genes have not been documented in mango. In this research, the mango (Mangifera indica) genome yielded four GID1 homologous genes, and this study focuses on the research of MiGID1A and MiGID1B genes.
View Article and Find Full Text PDFFunctionalization of slow-release fertilizers and "passive predation microplastics" mechanism for polylactic acid composites.
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The Key Laboratory of Advanced Textile Materials and Manufacturing Technology of Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, China. Electronic address:
The large-scale use of nonrenewable plastic mulch has resulted in serious agricultural health pollution. Biobased plastic materials with degradable properties offer attractive sustainable alternatives, but the shortcomings of their properties are slow degradation and extremely monofunctional, making their full-scale promotion still challenging. This work proposes a novel functionalized strategy for the multifunctionality empowerment of bio-based PLA materials for environmental protection and crop yield enhancement.
View Article and Find Full Text PDFDegradative removal of diclofenac from wastewater - Statistical and analytical approaches to understand degradation pathways.
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Université D'Artois, IUT de Béthune, 62400, Béthune, France; LASIRE, Equipe Physico-Chimie de L'Environnement, CNRS UMR 8516, Université de Lille, Sciences et Technologies, Villeneuve D'Ascq Cedex 59655, Lille, France. Electronic address:
In environmental management area, quality of water is a major growing concern with the emerging contaminants such as pesticides and pharmaceuticals likely to be present at low concentrations in water bodies, thereby potentially harming the ecosystem and human health. Diclofenac (DCF), a commonly used drug, has been found in wastewater, surface water, and drinking water sources, whose elimination can be a challenge issue. This study investigates the elimination of DCF by the photochemical method from aqueous media using short-wavelength radiation and hydrogen peroxide.
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