The cement industry has achieved the harmless and resourceful disposal of incineration fly ash, but the environmental safety of heavy metals during its service life is still unknown. Therefore, the evolution of heavy metal leaching during the wet-dry cycle of the incineration of fly ash after different solidification treatments has been studied. We provide a theoretical basis for the long-term safe use of incineration fly ash after resource utilization. The results showed that when incineration fly ash underwent 90 dry-wet cycles, the leaching of Cd exceeded 19.40% of Chinese standard GB 18598-2019. Upon addition of 10% and 30% cement to incineration fly ash, the trend of increasing leaching of heavy metals slowed, with a higher cement content enhancing the solidification capability for heavy metals. When incineration fly ash mixed with 10% cement underwent 180 dry-wet cycles, the leaching of Cd exceeded 40.75% of Chinese standard GB 18598-2019, while that of samples with 30% cement content did not exceed the limit, with Cd leaching at 84.45% of Chinese standard GB 18598-2019. As an admixture, the compressive strength increased with the number of dry-wet cycles. When the incineration fly ash dosage was 20%, the maximum leaching of heavy metals after 180 dry-wet cycles was only 5.19% of Chinese standard GB 18598-2019. The toxicity index of heavy metals also showed a decreasing trend compared with that of incineration fly ash. Therefore, cement admixture with incineration fly ash ensured the safety of heavy metals during its service life.
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http://dx.doi.org/10.1021/acs.langmuir.4c04272 | DOI Listing |
Langmuir
March 2025
State Key Laboratory of Solid Waste Reuse for Building Materials, Beijing Building Materials Academy of Sciences Research, Beijing 100041, China.
The cement industry has achieved the harmless and resourceful disposal of incineration fly ash, but the environmental safety of heavy metals during its service life is still unknown. Therefore, the evolution of heavy metal leaching during the wet-dry cycle of the incineration of fly ash after different solidification treatments has been studied. We provide a theoretical basis for the long-term safe use of incineration fly ash after resource utilization.
View Article and Find Full Text PDFJ Environ Manage
March 2025
Ningbo Innovation Center, Zhejiang University, Ningbo, 315100, China; State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou, 310027, China.
The melting/vitrification method is a promising approach for the large-scale, rapid, and harmless disposal of municipal solid waste incineration fly ash (MSWIFA). However, this method inevitably involves challenges related to secondary pollution. A 2 t/d pilot-scale melting furnace was built to investigate the distribution and migration of pollutant components-specifically heavy metals, sulfur, and chloride-within secondary fly ash (SFA), vitrified slag (VS), and ash in the flue gas channel (AFC) during the melting process of MSWIFA.
View Article and Find Full Text PDFEnviron Pollut
February 2025
State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, 510640, China.
Municipal solid waste incinerators (MSWIs) are deemed important sources of polychlorinated and polybrominated dibenzo-p-dioxin/furans (PCDD/Fs and PBDD/Fs). However, compared to PCDD/Fs, the emission characteristics of MSWI-derived PBDD/Fs have been rarely studied. Here we selected a long-term operating MSWI, investigated the generation of PBDD/Fs under varying incineration conditions within the normal range, and compared them to those of PCDD/Fs.
View Article and Find Full Text PDFJ Hazard Mater
February 2025
College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong 518060, China. Electronic address:
Chloride ion (Cl) contributes to the chelated incineration fly ash (CIFA) destabilization, yet there is limited research available on the effect of exogenous Cl corrosion. This study conducted 60-day column leaching experiments on fresh and aged CIFA (CIFA-F and CIFA-A), utilizing NaCl solutions at concentrations of 0 wt%, 1 wt%, and 3 wt%. It investigated the leaching behaviors of typical heavy metals (HMs) including lead, chromium, and nickel, associated with the leaching features like contents of calcium and dissolved organic matter (DOM), electrical conductivity, and pH.
View Article and Find Full Text PDFACS Omega
February 2025
School of Safety Science and Engineering, Anhui University of Science and Technology, Huainan 232001, China.
Municipal solid waste incineration (MSWI) fly ash (FA) is a hazardous waste produced during the incineration of municipal solid waste, posing a risk of heavy metal leaching and threatening the environment. Therefore, the harmless treatment of MSWI FA has become a crucial issue in environmental safety treatment. This study utilized blast furnace slag, FA, and MSWI FA to prepare composite alkali-activated cementitious materials for the solidification and stabilization of heavy metals in MSWI FA.
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