Energy storage technologies are critical for sustainable development, with electrolyte materials playing a decisive role in performance and safety. Single-ion conducting polymers (SICPs) represent a distinct materials class characterized by selective ion transport through immobilized ionic groups. While their potential for battery applications is recognized, an analysis of their sustainability implications and pathways to practical implementation has been lacking. This work demonstrates how strategic design of SICPs can contribute to sustainable energy storage through both materials development and device integration. Recent advances in lithium borate-based systems and CO2-derived polycarbonate architectures have achieved ionic conductivities exceeding 10-4 S cm-1 at room temperature through scalable synthesis routes. In lithium metal batteries, their high transference numbers and viscoelastic properties enable stable cycling with industrial-relevant cathode loadings, while as electrode binders, they enable aqueous processing and enhanced interfacial stability. Their versatility extends to sustainable chemistries, including sodium and zinc systems. Analysis reveals that while SICPs can enhance energy storage sustainability through improved performance, processability, and potential recyclability, opportunities remain in investigating end-of-life management. This work highlights frameworks for advancing SICP sustainability while maintaining the performance requirements for practical implementation in next-generation energy storage.
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http://dx.doi.org/10.1002/cssc.202500055 | DOI Listing |
Inorg Chem
March 2025
College of Energy Storage Technology, Shandong University of Science and Technology, Qingdao 266590, China.
Cesium-lead halide perovskite nanomaterials have been considered new-generation emitters that can meet the requirements of high photoluminescence efficiency and the high color standard of Rec. 2020. However, their practical application is currently hindered by the challenge of achieving better stability and growth in green solvents.
View Article and Find Full Text PDFChemistry
March 2025
Chongqing University, College of Materials Science and Engineering, CHINA.
Rechargeable magnesium batteries (RMBs) exhibit significant potential in large-scale energy storage due to their features of high volumetric capacity, resistance to dendrite formation, and abundant magnesium resources. However, the high polarity of divalent Mg2+ ions results in sluggish diffusion kinetics in conventional inorganic cathode materials, adversely affecting reversible capacity and rate performance. Organic materials such as pyrene-4,5,9,10-tetrone (PTO) and 3,4,9,10-perylenetetracarboxylic dianhydride (PTCDA), achieve rapid and reversible intercalation of magnesium ions through carbonyl enolization, but these materials are challenged by high cost, complex preparation, and poor environmental friendliness.
View Article and Find Full Text PDFPhys Chem Chem Phys
March 2025
School of Civil and Environmental Engineering, Cornell University, Ithaca, NY 14853, USA.
Hydrogen storage as hydrates is one of the most environmentally benign approaches to store hydrogen as it requires only water and traces of promoters. However, the scalability of storing hydrogen hydrate formation is hindered by the limited understanding of the structure, dynamics and energetics of hydrogen and promoters in the hydrate cages. In this study, molecular dynamics simulation configurations with different occupancy modes of H and tetrahydrofuran (THF) in the hydrate cages are investigated under the following scenarios: (i) two H molecules occupying the small cages, (ii) occupancy of H molecules in the THF-free large cages, and (iii) co-occupancy of H and THF in one large cage.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2025
Northwest Institute for Nonferrous Metal Research, Xi'an, Shannxi 710016, China.
Porous KTi(PO) nanoparticles are synthesized via a solvothermal method and subsequently modified with nitrogen-doped carbon layers by using polydopamine as the carbon source. The resultant KTi(PO)@N-doped carbon composite (KTP@NC) exhibits a preserved porous structure with abundant pores, facilitating ion diffusion and electrolyte infiltration. Various characterizations, including X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and Raman spectroscopy, reveal the successful formation of an interconnected nitrogen-doped carbon network.
View Article and Find Full Text PDFSmall
March 2025
The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin, 300071, China.
Photocatalytic hydrogen production through water splitting represents a promising strategy to store solar energy as chemical energy. Current photocatalysts primarily focus on traditional semiconductor materials, such as metal oxides, sulfides, nitrides, g-CN, etc. However, these materials often suffer from large bandgap and fast charge recombination, which limit sunlight utilization and result in unsatisfactory photon conversion efficiency.
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