Diphosphine-induced morphological modification in Au nanoclusters and its implications for catalytic activity regulation.

Chem Commun (Camb)

Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei, Anhui 230601, China.

Published: March 2025

Diphosphine-induced structural transformation was performed to modify the local structure of Au, leading to the formation of an Au nanocluster. The regular box-like morphology of Au is converted into a sharp shape for Au. This change in morphology results in the activity enhancement of Au in the photocatalytic degradation of rhodamine B.

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http://dx.doi.org/10.1039/d5cc00438aDOI Listing

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Diphosphine-induced morphological modification in Au nanoclusters and its implications for catalytic activity regulation.

Chem Commun (Camb)

March 2025

Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials and Institutes of Physical Science and Information Technology, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Anhui University, Hefei, Anhui 230601, China.

Diphosphine-induced structural transformation was performed to modify the local structure of Au, leading to the formation of an Au nanocluster. The regular box-like morphology of Au is converted into a sharp shape for Au. This change in morphology results in the activity enhancement of Au in the photocatalytic degradation of rhodamine B.

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