0.5%Au supported on γ-AlOOH and γ-AlO was used for low temperature oxidation of CO and aromatic alcohols. Various characterization techniques, including X-ray diffraction, N adsorption, FT-IR spectroscopy, XPS, TEM, CO-TPD and solid-state MAS NMR, were employed to characterize these catalysts. The Au/γ-AlOOH sample has abundant hydroxyl groups and basic sites on its surface, exhibiting strong adsorption for aromatic alcohols, and outstanding activity for low-temperature oxidation of aromatic alcohols. The Au/γ-AlO sample shows sufficient Au sites leading to high performance for low-temperature CO oxidation.
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http://dx.doi.org/10.1039/d5ra00527b | DOI Listing |
Environ Sci Pollut Res Int
March 2025
Department of Environmental Medicine, Faculty of Public Health, Institute of Health Protection, Slovak Medical University in Bratislava, Limbová 2651/12, 833 03, Bratislava, Slovakia.
Approximately 5 years ago, we proposed the establishment of a new category of ototoxicants: environmental ototoxicants, in addition to the recognized categories of occupational and drug-related ototoxicants. Since the publication of our review, the scientific literature has confirmed the potential for hearing impairment (HI) caused by the general population's exposure to various chemicals. However, the extent of this exposure's contribution to the global incidence of hearing loss (HL) has yet to be estimated.
View Article and Find Full Text PDFAcc Chem Res
March 2025
Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599 United States.
ConspectusAromatic functionalization reactions are some of the most fundamental transformations in organic chemistry and have been a mainstay of chemical synthesis for over a century. Reactions such as electrophilic and nucleophilic aromatic substitution (EAS and SAr, respectively) represent the two most fundamental reaction classes for arene elaboration and still today typify the most utilized methods for aromatic functionalization. Despite the reliable reactivity accessed by these venerable transformations, the chemical space that can be accessed by EAS and SAr reactions is inherently limited due to the electronic requirements of the substrate.
View Article and Find Full Text PDFHeliyon
February 2025
Brazilian Agricultural Research Corporation, Parque Estação Biológica, s/n, Av. Asa Norte, Brasília, CEP 70770-901, Brazil.
The lignin fraction of the lignocellulosic biomass corresponds to 15-30 % wt. This is largely obtained as a by-product of wood pulping to produce cellulose and paper, with the kraft process being the most used by industry. The chemical composition of lignin makes an excellent raw material for obtaining various chemical compounds with industrial applications, such as phenolic resins, biofuels and fine chemical products.
View Article and Find Full Text PDFFront Nutr
February 2025
College of Biomass Science and Engineering, Sichuan University, Chengdu, China.
This study investigated the metabolic characteristics of mulberry wine produced by co-fermentation with (SC) and two different (PK). Although inhibited the growth of during co-fermentation, showed robust growth adaptability. Classical oenological parameters were not significantly altered by co-fermentation compared to pure-fermentation.
View Article and Find Full Text PDFRSC Adv
March 2025
REZEL Catalysts Corp. Shanghai 201313 China +86-21-38280081.
0.5%Au supported on γ-AlOOH and γ-AlO was used for low temperature oxidation of CO and aromatic alcohols. Various characterization techniques, including X-ray diffraction, N adsorption, FT-IR spectroscopy, XPS, TEM, CO-TPD and solid-state MAS NMR, were employed to characterize these catalysts.
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