Heterostructures have promising applications in photonics and optoelectronics, mainly due to their high electron mobility and broadband photoresponse covering visible, infrared, and terahertz (THz) ranges. However, it is challenging to detect heterostructures in high definition with conventional THz techniques. Here we demonstrate a THz nanoscopic imaging method which is capable of resolving the local THz response of PbS-graphene heterostructures based upon a sophisticated THz near-field optical microscope. The interaction between the THz near field and the heterostructure is further explored by numerical simulations. The results reveal that both the composition and structure of the layers composing the heterostructure contribute to the THz signal. Furthermore, we develop a reliably finite dipole model suitable for retrieving THz optoelectronic properties of multilayered systems from measured THz hyperspectra, and realize mapping the local effective permittivity and conductivity of the heterostructure. Our work discloses the mechanism of the THz response of heterostructures, and provides a useful method for high-definition quantifying complex THz materials and devices.
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http://dx.doi.org/10.1021/acsnano.4c16185 | DOI Listing |
Langmuir
March 2025
Department of Information and Electrical Engineering and Applied Mathematics, University of Salerno, via Giovanni Paolo II 132, Fisciano, Salerno 84084, Italy.
The interaction between organic molecules and nanomaterials leads to complexation or the functionalization of later and modification of their properties, which are promising for electronics, terahertz technology, photonics, medical imaging, drug delivery, and other applications. Based on theoretical and experimental (THz, Raman, and fluorescence spectroscopy) studies, we analyzed the main spectroscopic characteristics of a weakly bound van der Waals complex of -stilbene (TS) molecule and hexagonal boron nitride (hBN). Raman scattering was demonstrated to be the most effective tool to confirm complex formation, exhibiting blue-shifted TS fingerprint lines in the TS + hBN Raman spectrum with respect to the spectra of pure TS or BN.
View Article and Find Full Text PDFAdv Mater
March 2025
Department of Electrical Engineering, University of Notre Dame, Notre Dame, IN, 46556, USA.
Programmable on-chip terahertz (THz) topological photonic devices are poised to address the rising need for high-capacity data systems, offering broad bandwidth, minimal loss, and reconfigurability. However, current THz topological chips rely on volatile tuning mechanisms that require continuous power to function. Here, a nonvolatile, programmable THz topological silicon chip is demonstrated that integrates a waveguide-cavity coupled system with phase-change material, GeSbTe (GST), enabling persistent and efficient functionality without constant power input.
View Article and Find Full Text PDFNanomaterials (Basel)
March 2025
Finance and Economics Department, Sanya University, Sanya 572022, China.
We demonstrate a thermally controlled ultra-wideband wide incident angle metamaterial absorber with switchable transmission at the THz band in this paper. The underlying hybrid structure of FSS-VO thin films make them switchable between absorption mode and transmission mode by controlling the temperature. It can achieve ultra-wideband absorption with above 90% absorption from 1 THz to 10 THz and exhibits excellent absorption performance under a wide range of incident and polarization angles at a high temperature (80 °C).
View Article and Find Full Text PDFTerahertz (THz) waves, a novel type of radiation with quantum and electronic properties, have attracted increasing attention for their effects on the nervous system. Spatial working memory, a critical component of higher cognitive function, is coordinated by brain regions such as the infralimbic cortex (IL) region of the medial prefrontal cortex and the ventral cornu ammonis 1 (vCA1) of hippocampus. However, the regulatory effects of THz waves on spatial working memory and the underlying mechanisms remain unclear.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2025
National Engineering Laboratory of Textile Fiber Materials and Processing Technology, College of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou 310018, PR China. Electronic address:
Tyrosine (Tyr) has gained significant attention as one of the most sensitive amino acids. Its oxidation is accompanied by changes in hydrogen bonds, so the oxidation process of Tyr is monitored and the dissociation sequence of different hydrogen bond network is elucidated based on the sensitivity of terahertz (THz) waves to intermolecular interactions. We find that the peak height of Tyr at 0.
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