The -decay fine structure of Hg and Au was studied by means of decay spectroscopy. Two experiments were performed at the Accelerator Laboratory of the University of Jyväskylä (JYFL), Finland, utilizing the recoil separator RITU and a digital data acquisition system. The heavy-ion induced fusion-evaporation reactions Kr + Ru and Kr + Mo were used to produce the Hg and Au nuclei, respectively. Studying the evaporation residues (ER, recoils)- - correlations and - coincidences, a new decay with E = 6156(10) keV was observed from Hg. This decay populates the (9/2 ) excited state at an excitation energy of 131.3(5) keV in Pt. The internal conversion coefficient for the 131.3(5) keV transition de-exciting this state was measured for the first time. Regarding the Au nucleus, a new decay with E = 5998(9) keV was observed to populate the 156.1(6) keV excited state in Ir. Two de-excitation paths were observed from this excited state. Moreover, a new 215.7(13) keV transition was observed to depopulate the 424.4(13) keV excited state in Ir. Properties of the Hg and Au decays were examined in a framework of reduced widths and hindrance factors. For clarity and simplicity, the spin and parity assignments (e.g. ) are presented without brackets throughout the text.
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http://dx.doi.org/10.1140/epja/s10050-025-01513-9 | DOI Listing |
Chempluschem
March 2025
Shanghai University, Chemistry, Shangda Road 99, 200444, Shanghai, CHINA.
Electrochemiluminescence (ECL) combines electrochemical redox processes with photochemical light emission, offering exceptional sensitivity, spatial control, and stability. Widely applied in biosensing, medical diagnostics, and environmental monitoring, its efficiency often depends on advanced catalytic materials. Single-atom catalysts (SACs), featuring isolated metal atoms dispersed on a support, have emerged as promising candidates due to their unique electronic structures, high atom utilization, and tunable catalytic properties.
View Article and Find Full Text PDFChemphyschem
March 2025
Universität Siegen, Physikalische Chemie, Adolf-Reichwein-Str. 2, 57076, Siegen, GERMANY.
Organic-inorganic halocuprates(I) form a promising class of light-emitting materials with high photoluminescence (PL) quantum yield. However, the understanding of their emission properties and the PL mechanism is still limited. Here, we investigate thin films of bis(tetrapropylammonium) hexa-µ-bromo-tetrahedro-tetracuprate(I), [N(C3H7)4]2[Cu4Br6], which has a zero-dimensional (0D) molecular salt structure containing [Cu4Br6]2- ions.
View Article and Find Full Text PDFJ Am Chem Soc
March 2025
Department of Chemistry, and the Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong 999077, PR China.
Research on room temperature phosphorescence (RTP) of metal-organic frameworks (MOFs) has been rapidly developed in recent years. However, it is still challenging to realize long-wavelength RTP (>580 nm). In this article, a new strategy is proposed to achieve the red-shifted RTP through constructing dual-ligand MOFs.
View Article and Find Full Text PDFComp Biochem Physiol A Mol Integr Physiol
March 2025
Department of Biological Sciences, California State University San Marcos, CA 92096, USA. Electronic address:
Salmonid fishes are well adapted to transition between salinities as part of a diadromid lifestyle, and many species are both economically and environmentally important. Ion-transporting gill epithelium helps fishes maintain ion balance during salinity transition. Recent transcriptomic surveys suggest that voltage-gated ion channels (VGICs) are present in gill epithelium of fishes.
View Article and Find Full Text PDFSci Adv
March 2025
Department of Electrical and Photonics Engineering, Technical University of Denmark, 2800 Kgs. Lyngby, Denmark.
We propose a mechanism for generating single photons in the mid-infrared (MIR) using a solid-state or molecular quantum emitter. The scheme uses cavity quantum electrodynamics (QED) effects to selectively enhance a Frank-Condon transition, deterministically preparing a single Fock state of a polar phonon mode. By coupling the phonon mode to an antenna, the resulting excitation is then radiated to the far field as a single photon with a frequency matching the phonon mode.
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