Severity: Warning
Message: file_get_contents(https://...@pubfacts.com&api_key=b8daa3ad693db53b1410957c26c9a51b4908&a=1): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
Filename: helpers/my_audit_helper.php
Line Number: 197
Backtrace:
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 197
Function: file_get_contents
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 271
Function: simplexml_load_file_from_url
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 1057
Function: getPubMedXML
File: /var/www/html/application/helpers/my_audit_helper.php
Line: 3175
Function: GetPubMedArticleOutput_2016
File: /var/www/html/application/controllers/Detail.php
Line: 575
Function: pubMedSearch_Global
File: /var/www/html/application/controllers/Detail.php
Line: 489
Function: pubMedGetRelatedKeyword
File: /var/www/html/index.php
Line: 316
Function: require_once
This paper further simplifies the gas state equation (EOS) by introducing a thermodynamic constant, , into the equation, a theoretical pressure that all gas converts into liquid. In the gas-liquid saturation system, linear regressions of ln -ln from M.P. to give = . It verifies Henry's law of gas solubility. Meanwhile, s for most substances are found in the range of 15-16, i.e., 3.269-8.886 MPa. Hence, EOS deforms into . Isotherm is a forced equilibrium system sustained by an outer force. Isothermal EOS is derived by differentiating heat over . , where or . Empolying Ar as an example, EOS are demonstrated over the whole pressure range, 0-1000 MPa, including the supercritical state. Applausive results are obtained in the pressure range before the gas-liquid transition and high temperatures (1000-2000 K), respectively. The supercritical state of intermediate temperatures (160-800 K) is likely liquid-like. Hence, EOS is not fittable.
Download full-text PDF |
Source |
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11886907 | PMC |
http://dx.doi.org/10.1021/acsomega.4c10390 | DOI Listing |
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