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Simplified Gas State Equations at Saturation and Isotherm. | LitMetric

Simplified Gas State Equations at Saturation and Isotherm.

ACS Omega

Anhui Lixing New Materials Lt. Co., Zhongwang Rd. 10, Jixi Industry District, Xuancheng 245300, Anhui Province, China.

Published: March 2025

This paper further simplifies the gas state equation (EOS) by introducing a thermodynamic constant, , into the equation, a theoretical pressure that all gas converts into liquid. In the gas-liquid saturation system, linear regressions of ln -ln from M.P. to give = . It verifies Henry's law of gas solubility. Meanwhile, s for most substances are found in the range of 15-16, i.e., 3.269-8.886 MPa. Hence, EOS deforms into . Isotherm is a forced equilibrium system sustained by an outer force. Isothermal EOS is derived by differentiating heat over . , where or . Empolying Ar as an example, EOS are demonstrated over the whole pressure range, 0-1000 MPa, including the supercritical state. Applausive results are obtained in the pressure range before the gas-liquid transition and high temperatures (1000-2000 K), respectively. The supercritical state of intermediate temperatures (160-800 K) is likely liquid-like. Hence, EOS is not fittable.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11886907PMC
http://dx.doi.org/10.1021/acsomega.4c10390DOI Listing

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