A recent development in our understanding of the theory of quantum fields is the fact that familiar gauge theories in spacetime dimensions greater than two can have non-invertible symmetries generated by topological defects. The hallmark of these non-invertible symmetries is that the fusion rule deviates from the usual group-like structure, and in particular the fusion coefficients take values in topological field theories (TFTs) rather than in mere numbers. In this paper we begin an exploration of the associativity structure of non-invertible symmetries in higher dimensions. The first layer of associativity is captured by F-symbols, which we find to assume values in TFTs that have one dimension lower than that of the defect. We undertake an explicit analysis of the F-symbols for the non-invertible chiral symmetry that is preserved by the massless QED and explore their physical implications. In particular, we show the F-symbol TFTs can be detected by probing the correlators of topological defects with 't Hooft lines. Furthermore, we derive the Ward-Takahashi identity that arises from the chiral symmetry on a large class of four-dimensional manifolds with non-trivial topologies directly from the topological data of the symmetry defects, without referring to a Lagrangian formulation of the theory.
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http://dx.doi.org/10.1007/s00220-024-05227-9 | DOI Listing |
J Phys Condens Matter
March 2025
Molecular PhotoScience Research Center, Kobe University, Rokkoudai 1-1, Kobe, Hyogo, 657-8501, JAPAN.
Recent theoretical and experimental studies on the frustration-induced skyrmion crystal (SkX) in centrosymmetric magnets are reviewed, with some emphasis on their symmetry and topological aspects. Special importance of frustration and chirality is highlighted. Theories cover the studies based on both the spin models and the electronic models.
View Article and Find Full Text PDFCommun Math Phys
March 2025
Center for Cosmology and Particle Physics, New York University, New York, USA.
A recent development in our understanding of the theory of quantum fields is the fact that familiar gauge theories in spacetime dimensions greater than two can have non-invertible symmetries generated by topological defects. The hallmark of these non-invertible symmetries is that the fusion rule deviates from the usual group-like structure, and in particular the fusion coefficients take values in topological field theories (TFTs) rather than in mere numbers. In this paper we begin an exploration of the associativity structure of non-invertible symmetries in higher dimensions.
View Article and Find Full Text PDFAnnu Rev Chem Biomol Eng
March 2025
1Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois, USA; email:
Chirality, a fundamental attribute of asymmetry, pervades in both nature and functional soft materials. In chiral material systems design, achieving global symmetry breaking of building blocks during assembly, with or without the aid of additives, has emerged as a promising strategy across domains including chiral sensing, electronics, photonics, spintronics, and biomimetics. We first introduce the fundamental aspects of chirality, including its structural basis and symmetry-breaking mechanisms considering free energy minimization.
View Article and Find Full Text PDFNano Lett
March 2025
Department of Physics and Astronomy, Seoul National University, Seoul 08826, Republic of Korea.
Reducing the dimensionality in layered materials typically yields properties distinct from bulk properties. In systems with broken inversion symmetry, strong spin-orbit coupling induces relativistic electron interactions such as the Rashba-Edelstein effect (REE). Initially proposed in two-dimensional magnets, applying the REE theory to real three-dimensional systems poses challenges, necessitating experimental validation.
View Article and Find Full Text PDFAnal Chim Acta
April 2025
Centro Nazionale per il Controllo e la Valutazione dei Farmaci, Istituto Superiore di Sanità, Viale Regina Elena 299, 00161, Rome, Italy. Electronic address:
Background: Planar chiral ferrocenes are well-established metallocenes that have attracted considerable attention for several decades due to their potential applications in synthesis, catalysis, materials science and medicinal chemistry. The planar stereogenicity of these compounds occurs when the symmetry plane of a single planar ring is broken by the introduction of two or more different substituents. Recently, the range of applications of planar chiral ferrocenes has been further extended by using them as model systems to investigate the enantioselective properties of inherently chiral materials incorporated into electrochemical devices and polysaccharide-based chiral stationary phases used for enantioselective HPLC.
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